DOI: 10.1063/1.1674019. Infrared Spectra of Matrix-Isolated Hydrogen Sulfide in Solid Nitrogen [Penn]

Infrared Spectra of Matrix-Isolated Hydrogen Sulfide in Solid Nitrogen

10.1063/1.1674019

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The infrared spectra of H2S in a series of solid nitrogen matrices at 20°K are recorded for the 2500–4000-cm−1 region. From a curve-resolution analysis of the SH stretching region, assignments of peaks are made to monomer, dimer, and polymer species. The H2S dimer absorptions lead to a postulated open structure with a single hydrogen bond. An estimate based on frequency-shift data indicates a hydrogen bond strength of roughly half that found in the matrix-isolated water dimer.

Bibliography

Tursi, A. J., & Nixon, E. R. (1970). Infrared Spectra of Matrix-Isolated Hydrogen Sulfide in Solid Nitrogen. The Journal of Chemical Physics, 53(2), 518â521.

Authors 2

Anthony J. Tursi (first)
Eugene R. Nixon (additional)

References 8 Referenced 44

10.1063/1.1673163 / J. Chem. Phys. (1970)
10.1063/1.1743164 / J. Chem. Phys. (1956)
10.1063/1.1732540 / J. Chem. Phys. (1962)
{'key': '2024020906465710700_r4'}
10.1351/pac196307010111 / Pure Appl. Chem. (1963)
10.1016/0022-4073(70)90126-3 / J. Quant. Spectry. Radiative Transfer (1970)
{'key': '2024020906465710700_r7'}
{'key': '2024020906465710700_r8'}

Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 3:15 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 2:19 a.m.)
Indexed	3 days, 11 hours ago (Aug. 22, 2025, 12:46 a.m.)
Issued	55 years, 1 month ago (July 15, 1970)
Published	55 years, 1 month ago (July 15, 1970)
Published Print	55 years, 1 month ago (July 15, 1970)

Funders 0

None

BibTeX

@article{Tursi_1970, title={Infrared Spectra of Matrix-Isolated Hydrogen Sulfide in Solid Nitrogen}, volume={53}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1674019}, DOI={10.1063/1.1674019}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Tursi, Anthony J. and Nixon, Eugene R.}, year={1970}, month=jul, pages={518–521} }

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