DOI: 10.1063/1.1673607. Bulk Trapping States in β-Phthalocyanine Single Crystals

Bulk Trapping States in β-Phthalocyanine Single Crystals

10.1063/1.1673607

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

From temperature dependence measurements of the SCLC and Ohmic current densities, the electron trapping levels in metal-free phthalocyanine have been determined in several ambients. In vacuum, traps with a density 5 × 1019 cm−3 located 0.38 eV below the conduction band have been observed. Associated with this level are donor sites with a density 2 × 1012 cm−3. In oxygen and hydrogen, trapping sites near the middle of the bandgap are observed. Thickness dependence measurements prove that the trapping sites are located at discrete energy levels. The results are extended to comment upon traps in copper phthalocyanine. The measurements indicate that the electron mobility is not temperature dependent up to 373°K.

Bibliography

Barbe, D. F., & Westgate, C. R. (1970). Bulk Trapping States in Î²-Phthalocyanine Single Crystals. The Journal of Chemical Physics, 52(8), 4046â4054.

Authors 2

D. F. Barbe (first)
C. R. Westgate (additional)

References 22 Referenced 69

{'key': '2024020906163756000_r1'}
10.1016/0022-3697(69)90004-3 / J. Phys. Chem. Solids (1969)
{'key': '2024020906163756000_r3', 'first-page': '163', 'volume': '38', 'year': '1962', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1962)
10.1063/1.1840699 / J. Chem. Phys. (1967)
10.1103/PhysRev.132.2010 / Phys. Rev. (1963)
10.1063/1.1670963 / J. Chem. Phys. (1969)
{'key': '2024020906163756000_r7', 'first-page': '236', 'volume': '2', 'year': '1969', 'journal-title': 'J. Chem. Soc. A'} / J. Chem. Soc. A (1969)
{'key': '2024020906163756000_r8', 'first-page': '2738', 'volume': '30', 'year': '1967', 'journal-title': 'J. Appl. Phys.'} / J. Appl. Phys. (1967)
10.1063/1.1702729 / J. Appl. Phys. (1963)
{'key': '2024020906163756000_r10', 'first-page': '772', 'volume': '4', 'year': '1962', 'journal-title': 'Fiz. Tverd. Tela.'} / Fiz. Tverd. Tela. (1962)
{'key': '2024020906163756000_r10a', 'first-page': '566', 'volume': '4', 'year': '1962', 'journal-title': 'Sov. Phys.-Solid State'} / Sov. Phys.-Solid State (1962)
{'key': '2024020906163756000_r11'}
10.1103/PhysRev.103.1648 / Phys. Rev. (1956)
{'key': '2024020906163756000_r13'}
{'key': '2024020906163756000_r14', 'first-page': '537', 'volume': '28A', 'year': '1969', 'journal-title': 'Phys. Letters'} / Phys. Letters (1969)
10.1063/1.1840436 / J. Chem. Phys. (1967)
{'key': '2024020906163756000_r16'}
10.1063/1.1727331 / J. Chem. Phys. (1966)
10.1143/JPSJ.25.431 / J. Phys. Soc. Japan (1968)
10.1002/pssb.19670200129 / Phys. Status Solidi (1967)
10.1002/pssb.19660150108 / Phys. Status Solidi (1966)
10.1002/pssb.19630031015 / Phys. Status Solidi (1963)

Dates

Type	When
Created	21 years, 7 months ago (Feb. 6, 2004, 2:23 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 1:42 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 12:26 a.m.)
Issued	55 years, 4 months ago (April 15, 1970)
Published	55 years, 4 months ago (April 15, 1970)
Published Print	55 years, 4 months ago (April 15, 1970)

Funders 0

None

BibTeX

@article{Barbe_1970, title={Bulk Trapping States in β-Phthalocyanine Single Crystals}, volume={52}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1673607}, DOI={10.1063/1.1673607}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Barbe, D. F. and Westgate, C. R.}, year={1970}, month=apr, pages={4046–4054} }

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