Abstract
A fluorescence of alkali halide single crystals doped with the corresponding alkali hydroxide has been observed and is attributed to the A 2Σ+ → X 2Π emission of a photoproduced hydroxyl radical. A phosphorescence of systems containing the hydroxide ion has also been noted at λ ∼ 400 mμ and is attributed to a Σ−4 → X 2Π emission of the OH radical. Photoprocesses in systems containing the OH− ion, as well as in aqueous systems containing certain salts and acids, are discussed in a qualitative way.
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Dates
Type | When |
---|---|
Created | 21 years, 6 months ago (Feb. 6, 2004, 2:23 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 9, 2024, 1:39 a.m.) |
Indexed | 2 months, 1 week ago (June 27, 2025, 3:44 p.m.) |
Issued | 55 years, 5 months ago (April 1, 1970) |
Published | 55 years, 5 months ago (April 1, 1970) |
Published Print | 55 years, 5 months ago (April 1, 1970) |
@article{Maria_1970, title={Luminescence of Systems Containing Hydroxyl Ion}, volume={52}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1673503}, DOI={10.1063/1.1673503}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Maria, H. J. and McGlynn, S. P.}, year={1970}, month=apr, pages={3402–3408} }