DOI: 10.1063/1.1673460. Pulse Radiolysis Studies. XVI. Kinetics of the Reaction of Gaseous Hydrogen Atoms with Molecular Oxygen by Fast Lyman-<i>α</i> Absorption Spectrophotometry

Pulse Radiolysis Studies. XVI. Kinetics of the Reaction of Gaseous Hydrogen Atoms with Molecular Oxygen by Fast Lyman-α Absorption Spectrophotometry

10.1063/1.1673460

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The pulse radiolysis method has been used to produce ground-state hydrogen atoms in gaseous hydrogen and has been combined with fast Lyman-α absorption spectrophotometry to observe these atoms directly with microsecond time resolution. The technique has been used to study the kinetics of the reaction H + O2 + M = HO2 + M, where M is H2. The rate constant for this reaction was found to have the value (1.7 ± 0.4) × 1010M−2·sec−1 at 298°K. This value, together with earlier data for Ar as third body, gives kH2 / kAr = 2.0 at 298°K for the ratio of the efficiencies of H2 and Ar as third body in this reaction.

Bibliography

Bishop, W. P., & Dorfman, L. M. (1970). Pulse Radiolysis Studies. XVI. Kinetics of the Reaction of Gaseous Hydrogen Atoms with Molecular Oxygen by Fast Lyman-Î± Absorption Spectrophotometry. The Journal of Chemical Physics, 52(6), 3210â3216.

Authors 2

W. P. Bishop (first)
Leon M. Dorfman (additional)

References 31 Referenced 31

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Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 2:23 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 1:39 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 4:01 p.m.)
Issued	55 years, 5 months ago (March 15, 1970)
Published	55 years, 5 months ago (March 15, 1970)
Published Print	55 years, 5 months ago (March 15, 1970)

Funders 0

None

BibTeX

@article{Bishop_1970, title={Pulse Radiolysis Studies. XVI. Kinetics of the Reaction of Gaseous Hydrogen Atoms with Molecular Oxygen by Fast Lyman-α Absorption Spectrophotometry}, volume={52}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1673460}, DOI={10.1063/1.1673460}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Bishop, W. P. and Dorfman, Leon M.}, year={1970}, month=mar, pages={3210–3216} }

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