DOI: 10.1063/1.1671982. Oxygen Isotope Fractionation in Divalent Metal Carbonates

Oxygen Isotope Fractionation in Divalent Metal Carbonates

10.1063/1.1671982

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Equilibrium fractionation factors for the distribution of 18O between alkaline-earth carbonates and water have been measured over the temperature range 0–500°C. The fractionation factors α can be represented by the equationsCaCO3–H2O, 1000 lnα = 2.78(106 T−2)− 3.39,SrCO3–H2O, 1000 lnα = 2.69(106 T−2)− 3.74,BaCO3–H2O, 1000 lnα = 2.57(106 T−2)− 4.73.Measurements on MnCO3, CdCO3, and PbCO3 were made at isolated temperatures. A statistical-mechanical calculation of the isotopic partition function ratios gives reasonably good agreement with experiment. Both cationic size and mass are important in isotopic fractionation, the former predominantly in its effect on the internal vibrations of the anion, the latter in its effect on the lattice vibrations.

Bibliography

OâNeil, J. R., Clayton, R. N., & Mayeda, T. K. (1969). Oxygen Isotope Fractionation in Divalent Metal Carbonates. The Journal of Chemical Physics, 51(12), 5547â5558.

Authors 3

James R. O'Neil (first)
Robert N. Clayton (additional)
Toshiko K. Mayeda (additional)

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Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 2:22 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 1:25 a.m.)
Indexed	25 minutes ago (Aug. 27, 2025, 12:29 p.m.)
Issued	55 years, 8 months ago (Dec. 15, 1969)
Published	55 years, 8 months ago (Dec. 15, 1969)
Published Print	55 years, 8 months ago (Dec. 15, 1969)

Funders 0

None

BibTeX

@article{O_Neil_1969, title={Oxygen Isotope Fractionation in Divalent Metal Carbonates}, volume={51}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1671982}, DOI={10.1063/1.1671982}, number={12}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={O’Neil, James R. and Clayton, Robert N. and Mayeda, Toshiko K.}, year={1969}, month=dec, pages={5547–5558} }

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  "abstract": "<jats:p>Equilibrium fractionation factors for the distribution of 18O between alkaline-earth carbonates and water have been measured over the temperature range 0\u2013500\u00b0C. The fractionation factors \u03b1 can be represented by the equationsCaCO3\u2013H2O, 1000 ln\u03b1\u2009=\u20092.78(106 T\u22122)\u2212\u20093.39,SrCO3\u2013H2O, 1000 ln\u03b1\u2009=\u20092.69(106 T\u22122)\u2212\u20093.74,BaCO3\u2013H2O, 1000 ln\u03b1\u2009=\u20092.57(106 T\u22122)\u2212\u20094.73.Measurements on MnCO3, CdCO3, and PbCO3 were made at isolated temperatures. A statistical-mechanical calculation of the isotopic partition function ratios gives reasonably good agreement with experiment. Both cationic size and mass are important in isotopic fractionation, the former predominantly in its effect on the internal vibrations of the anion, the latter in its effect on the lattice vibrations.</jats:p>",
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