DOI: 10.1063/1.1671617. ESR Measurement of Quadrupole Coupling in N(SO3)22−

ESR Measurement of Quadrupole Coupling in N(SO3)22−

10.1063/1.1671617

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The so-called second-order transitions in ESR spectra, which involve a change in both electron and nuclear spin, are sensitive to electric quadrupole coupling. The quadrupole interaction for 14N in N(SO3)22− was studied by observation of these transitions at 31.5 GHz in single crystals of γ-irradiated potassium aminedisulfonate. The resulting spectra can be explained assuming the principal axis system of the field-gradient tensor is the same as the hyperfine coupling tensor. The coupling constants then become e2Qqx′x′ = − 5.2 ± 1.4 MHz and e2Qqy′y′ = + 3.2 ± 1.0 MHz, where the x′ and y′ principal axes have direction cosines of (0.829, 0, 0.559) and (0, 1.0, 0) in an a* bc axis system.

Bibliography

Close, D. M., & Rexroad, H. N. (1969). ESR Measurement of Quadrupole Coupling in N(SO3)22â. The Journal of Chemical Physics, 50(9), 3717â3721.

Authors 2

David M. Close (first)
Harvey N. Rexroad (additional)

References 12 Referenced 8

10.1080/00268976200100261 / Mol. Phys. (1962)
10.1063/1.1700912 / J. Chem. Phys. (1960)
10.1021/ja01489a002 / J. Am. Chem. Soc. (1960)
10.1063/1.1695694 / J. Chem. Phys. (1965)
10.1016/S0371-1951(62)80137-4 / Spectrochim. Acta (1962)
10.1021/ja01275a064 / J. Am. Chem. Soc. (1938)
{'key': '2024020904544575000_r7'}
10.1107/S0365110X56000796 / Acta Cryst. (1956)
{'key': '2024020904544575000_r9', 'first-page': '620', 'volume': '13', 'year': '1968', 'journal-title': 'Bull. Am. Phys. Soc.'} / Bull. Am. Phys. Soc. (1968)
10.1063/1.1747400 / J. Chem. Phys. (1949)
{'key': '2024020904544575000_r11', 'first-page': '285', 'volume': '240', 'year': '1955', 'journal-title': 'Compt. Rend.'} / Compt. Rend. (1955)
{'key': '2024020904544575000_r12', 'first-page': '77', 'volume': '77', 'year': '1951', 'journal-title': 'Phys. Rev.'} / Phys. Rev. (1951)

Dates

Type	When
Created	21 years, 7 months ago (Feb. 4, 2004, 4:37 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 11:57 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 11:27 a.m.)
Issued	56 years, 4 months ago (May 1, 1969)
Published	56 years, 4 months ago (May 1, 1969)
Published Print	56 years, 4 months ago (May 1, 1969)

Funders 0

None

BibTeX

@article{Close_1969, title={ESR Measurement of Quadrupole Coupling in N(SO3)22−}, volume={50}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1671617}, DOI={10.1063/1.1671617}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Close, David M. and Rexroad, Harvey N.}, year={1969}, month=may, pages={3717–3721} }

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