DOI: 10.1063/1.1671537. Neutralization of Isolated Ion Pair in Polar Media. II. Evolution of the Neutralization Process

Neutralization of Isolated Ion Pair in Polar Media. II. Evolution of the Neutralization Process

10.1063/1.1671537

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

In this paper we discuss the neutralization rate of an isolated ion pair in a polar medium as obtained from the prescribed diffusion solution of the Smoluchowski equation. Specifically, we consider the cases of water, methanol, and ammonia. A specific model with two diffusion constants and a time-dependent dielectric constant has been employed. The time dependence of the dielectric constant is taken, as in the previous paper, for the situation of fixed charge rather than for fixed external field. Numerical results have been obtained for the probability that the ion pair remains unneutralized at a given time and for the rate of change of this probability with time. A critical review is presented for the time–distance relationship.

Bibliography

Mozumder, A. (1969). Neutralization of Isolated Ion Pair in Polar Media. II. Evolution of the Neutralization Process. The Journal of Chemical Physics, 50(8), 3162â3170.

Authors 1

A. Mozumder (first)

References 12 Referenced 16

10.1063/1.1712059 / J. Chem. Phys. (1967)
10.1103/PhysRev.54.554 / Phys. Rev. (1938)
10.1063/1.1668892 / J. Chem. Phys. (1968)
{'key': '2024020905040456800_r4'}
10.1103/RevModPhys.15.1 / Rev. Mod. Phys. (1943)
10.1021/ja01073a010 / J. Am. Chem. Soc. (1964)
{'key': '2024020905040456800_r7'}
10.1063/1.1669740 / J. Chem. Phys. (1968)
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Dates

Type	When
Created	21 years, 6 months ago (Feb. 4, 2004, 4:37 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 12:14 a.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 2:28 p.m.)
Issued	56 years, 4 months ago (April 15, 1969)
Published	56 years, 4 months ago (April 15, 1969)
Published Print	56 years, 4 months ago (April 15, 1969)

Funders 0

None

BibTeX

@article{Mozumder_1969, title={Neutralization of Isolated Ion Pair in Polar Media. II. Evolution of the Neutralization Process}, volume={50}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1671537}, DOI={10.1063/1.1671537}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Mozumder, A.}, year={1969}, month=apr, pages={3162–3170} }

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