DOI: 10.1063/1.1670573. Statistical Theory of Dissociation and Recombination for Moderately Complex Molecules

Statistical Theory of Dissociation and Recombination for Moderately Complex Molecules

10.1063/1.1670573

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The dissociation and recombination of moderately complex molecules in a background of inert atoms has been investigated using a master equation with transition probabilities and spontaneous decay rates obtained from the statistical theory of reaction rates. A relatively simple expression has been derived for the steady-state dissociation rate constant which is valid at all pressures for molecules containing three or more atoms. This expression has been used with reasonable success to correlate the available experimental data for 21 molecules having from three to six atoms.

Bibliography

Keck, J., & Kalelkar, A. (1968). Statistical Theory of Dissociation and Recombination for Moderately Complex Molecules. The Journal of Chemical Physics, 49(7), 3211â3223.

Authors 2

James Keck (first)
Ashok Kalelkar (additional)

References 36 Referenced 45

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Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 2:22 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 11:01 p.m.)
Indexed	11 months, 3 weeks ago (Aug. 31, 2024, 5:27 a.m.)
Issued	56 years, 10 months ago (Oct. 1, 1968)
Published	56 years, 10 months ago (Oct. 1, 1968)
Published Print	56 years, 10 months ago (Oct. 1, 1968)

Funders 0

None

BibTeX

@article{Keck_1968, title={Statistical Theory of Dissociation and Recombination for Moderately Complex Molecules}, volume={49}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1670573}, DOI={10.1063/1.1670573}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Keck, James and Kalelkar, Ashok}, year={1968}, month=oct, pages={3211–3223} }

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