DOI: 10.1063/1.1670468. Binary Diffusion and Bulk Flow through a Potential-Energy Profile: A Kinetic Basis for the Thermodynamic Equations of Flow through Membranes

Binary Diffusion and Bulk Flow through a Potential-Energy Profile: A Kinetic Basis for the Thermodynamic Equations of Flow through Membranes

10.1063/1.1670468

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The flow of a two-component solution through a potential-energy profile is analyzed in detail. The thermodynamic flow equations of Kedem and Katchalsky are derived, along with the Onsager reciprocal relation—the equality of the osmotic-flow coefficient and the ultrafiltration coefficient. Expressions are obtained for the solute permeability ω and the Staverman reflection coefficient σ. It is demonstrated that contributions from equilibrium partitioning and “frictional” effects both arise from the characteristics of the energy profile. The role of the pressure gradient as the driving force for osmotic flow is stressed.

Bibliography

Manning, G. S. (1968). Binary Diffusion and Bulk Flow through a Potential-Energy Profile: A Kinetic Basis for the Thermodynamic Equations of Flow through Membranes. The Journal of Chemical Physics, 49(6), 2668â2675.

Authors 1

Gerald S. Manning (first)

References 21 Referenced 41

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Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 2:22 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 11:09 p.m.)
Indexed	1 month, 2 weeks ago (July 8, 2025, 10:07 a.m.)
Issued	56 years, 11 months ago (Sept. 15, 1968)
Published	56 years, 11 months ago (Sept. 15, 1968)
Published Print	56 years, 11 months ago (Sept. 15, 1968)

Funders 0

None

BibTeX

@article{Manning_1968, title={Binary Diffusion and Bulk Flow through a Potential-Energy Profile: A Kinetic Basis for the Thermodynamic Equations of Flow through Membranes}, volume={49}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1670468}, DOI={10.1063/1.1670468}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Manning, Gerald S.}, year={1968}, month=sep, pages={2668–2675} }

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