DOI: 10.1063/1.1670372. Infrared and Raman Investigation of Condensed Phases of Methylamine and Its Deuterium Derivatives

Infrared and Raman Investigation of Condensed Phases of Methylamine and Its Deuterium Derivatives

10.1063/1.1670372

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The infrared spectra of solid and matrix-isolated methylamine, methylamine-d2, methyl-d3-amine, and methyl-d3-amine-d2 have been recorded from 4000 to 250 cm−1. The Raman spectra of the four isotopic species have also been recorded and depolarization values measured. The elusive NH2 twisting vibration has been located in the solid-phase infrared spectra of CH3NH2 and CD3NH2, and the assignment is in agreement with both the product rule and earlier assignments for this normal mode in hydrazine. A temperature-dependent hydrogen-bonding study has been carried out and ΔH° for H-bond formation in methylamine-d2 was found to be −660 cal/mole.

Bibliography

Durig, J. R., Bush, S. F., & Baglin, F. G. (1968). Infrared and Raman Investigation of Condensed Phases of Methylamine and Its Deuterium Derivatives. The Journal of Chemical Physics, 49(5), 2106â2117.

Authors 3

J. R. Durig (first)
S. F. Bush (additional)
F. G. Baglin (additional)

References 38 Referenced 77

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Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 2:22 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 11:07 p.m.)
Indexed	4 weeks, 2 days ago (Aug. 6, 2025, 8:59 a.m.)
Issued	57 years ago (Sept. 1, 1968)
Published	57 years ago (Sept. 1, 1968)
Published Print	57 years ago (Sept. 1, 1968)

Funders 0

None

BibTeX

@article{Durig_1968, title={Infrared and Raman Investigation of Condensed Phases of Methylamine and Its Deuterium Derivatives}, volume={49}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1670372}, DOI={10.1063/1.1670372}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Durig, J. R. and Bush, S. F. and Baglin, F. G.}, year={1968}, month=sep, pages={2106–2117} }

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