DOI: 10.1063/1.1670194. Hydrogen-Bond Studies. XXX. The Crystal Structure of Hydrogen Bromide Tetrahydrate, (H7O3)+(H9O4)+2Br−·H2O

Hydrogen-Bond Studies. XXX. The Crystal Structure of Hydrogen Bromide Tetrahydrate, (H7O3)+(H9O4)+2Br−·H2O

10.1063/1.1670194

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The crystal structure of hydrogen bromide tetrahydrate (HBr·4H2O) has been determined from three-dimensional single-crystal x-ray data recorded at −180°C. Crystals of this compound are monoclinic, space group P21, with four formula units in a cell with the dimensions: a = 7.043, b = 11.466, c = 7.339 Å, β = 110.85°. The structure determination shows that the compound may be formulated as (H7O3)+(H9O4)+2Br−·H2O. The hydrogen-bond lengths within H7O3+ are 2.465 and 2.498 Å, and within H9O4+2.496, 2.587, and 2.588 Å. Other O–H···O bonds in the structure are about 2.75 Å.

Bibliography

Lundgren, J.-O., & Olovsson, I. (1968). Hydrogen-Bond Studies. XXX. The Crystal Structure of Hydrogen Bromide Tetrahydrate, (H7O3)+(H9O4)+2BrâÂ·H2O. The Journal of Chemical Physics, 49(3), 1068â1074.

Authors 2

Jan-Olof Lundgren (first)
Ivar Olovsson (additional)

References 15 Referenced 38

10.1063/1.1670193 / J. Chem. Phys. (1968)
10.1107/S0365110X6700413X / Acta Cryst. (1967)
10.1107/S0365110X67004141 / Acta Cryst. (1967)
10.1524/zpch.1954.1.5_6.340 / Z. Physik. Chem. (Frankfurt) (1954)
{'key': '2024020903453475300_r5', 'first-page': '311', 'volume': '43', 'year': '1964', 'journal-title': 'Z. Physik. Chem. (Frankfurt)'} / Z. Physik. Chem. (Frankfurt) (1964)
{'key': '2024020903453475300_r6', 'first-page': '13', 'volume': '21', 'year': '1962', 'journal-title': 'Arkiv Fysik'} / Arkiv Fysik (1962)
{'key': '2024020903453475300_r7', 'first-page': '437', 'volume': '16', 'year': '1960', 'journal-title': 'Arkiv Kemi'} / Arkiv Kemi (1960)
10.1080/14786449308620454 / Phil. Mag. (1893)
{'key': '2024020903453475300_r9'}
10.1524/zpch.1966.48.1_2.001 / Z. Physik. Chem. (Frankfurt) (1966)
{'key': '2024020903453475300_r11'}
10.3891/acta.chem.scand.21-1206 / Acta Chem. Scand. (1967)
{'key': '2024020903453475300_r13'}
{'key': '2024020903453475300_r14'}
{'key': '2024020903453475300_r15'}

Dates

Type	When
Created	21 years, 7 months ago (Feb. 6, 2004, 2:22 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 10:48 p.m.)
Indexed	2 months ago (July 4, 2025, 8:45 a.m.)
Issued	57 years, 1 month ago (Aug. 1, 1968)
Published	57 years, 1 month ago (Aug. 1, 1968)
Published Print	57 years, 1 month ago (Aug. 1, 1968)

Funders 0

None

BibTeX

@article{Lundgren_1968, title={Hydrogen-Bond Studies. XXX. The Crystal Structure of Hydrogen Bromide Tetrahydrate, (H7O3)+(H9O4)+2Br−·H2O}, volume={49}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1670194}, DOI={10.1063/1.1670194}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Lundgren, Jan-Olof and Olovsson, Ivar}, year={1968}, month=aug, pages={1068–1074} }

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