DOI: 10.1063/1.1670109. 11B NMR in Polycrystalline Calcium Metaborate

11B NMR in Polycrystalline Calcium Metaborate

10.1063/1.1670109

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Boron-11 nuclear magnetic resonance has been observed in polycrystalline calcium metaborate doped with paramagnetic Mn2+. The spectrum arises from the m = 12↔m= − 12 transition broadened in second order by a quadrupole interaction having a nonzero asymmetry parameter. The quadrupole coupling constant of 2.58 ± 0.02 MHz is consistent with previously published values for three-coordinated boron. However, the electric field gradient asymmetry parameter of 0.55 ± 0.01 is several times greater than expected, and this large value is attributed to the presence of a nonbridging oxygen in the boron coordination shell. The possibility of using this result for the study of noncrystalline solids is discussed.

Bibliography

Kriz, H. M., Bishop, S. G., & Bray, P. J. (1968). 11B NMR in Polycrystalline Calcium Metaborate. The Journal of Chemical Physics, 49(2), 557â561.

Authors 3

H. M. Kriz (first)
S. G. Bishop (additional)
P. J. Bray (additional)

References 32 Referenced 42

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Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 2:22 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 10:48 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 7:59 a.m.)
Issued	57 years, 1 month ago (July 15, 1968)
Published	57 years, 1 month ago (July 15, 1968)
Published Print	57 years, 1 month ago (July 15, 1968)

Funders 0

None

BibTeX

@article{Kriz_1968, title={11B NMR in Polycrystalline Calcium Metaborate}, volume={49}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1670109}, DOI={10.1063/1.1670109}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Kriz, H. M. and Bishop, S. G. and Bray, P. J.}, year={1968}, month=jul, pages={557–561} }

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