DOI: 10.1063/1.1669740. Kinetics of Ionic Processes in the Radiolysis of Liquids. IV. Geminate Recombination of Ions

Kinetics of Ionic Processes in the Radiolysis of Liquids. IV. Geminate Recombination of Ions

10.1063/1.1669740

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

An estimate is made of the dispersion in the recombination time for ions undergoing diffusive recombination from an initial separation distance r. Then, an elementary method is used to obtain the least distance of ionic approach for which the Nernst–Einstein relation describes the motion of the ions. The inclusion of these considerations does not seriously affect the dependence of recombination time on r3 for r values between 40 and 120 Å in liquids of low dielectric constant (ε ≈ 2) at 300°K.

Bibliography

Williams, F. (1968). Kinetics of Ionic Processes in the Radiolysis of Liquids. IV. Geminate Recombination of Ions. The Journal of Chemical Physics, 48(9), 4077â4078.

Authors 1

Ffrancon Williams (first)

References 6 Referenced 14

10.1021/ja01073a010 / J. Am. Chem. Soc. (1964)
10.1063/1.1726646 / J. Chem. Phys. (1966)
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10.1063/1.1699113 / J. Chem. Phys. (1953)
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Dates

Type	When
Created	21 years, 6 months ago (Feb. 4, 2004, 4:33 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 10:30 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 2:29 a.m.)
Issued	57 years, 3 months ago (May 1, 1968)
Published	57 years, 3 months ago (May 1, 1968)
Published Print	57 years, 3 months ago (May 1, 1968)

Funders 0

None

BibTeX

@article{Williams_1968, title={Kinetics of Ionic Processes in the Radiolysis of Liquids. IV. Geminate Recombination of Ions}, volume={48}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1669740}, DOI={10.1063/1.1669740}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Williams, Ffrancon}, year={1968}, month=may, pages={4077–4078} }

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