Abstract
The equations for the relaxation time of a nuclear spin in a molecule undergoing diffusion reorientation have been extended to include fully anisotropic reorientation for a number of relaxation mechanisms. The full rotational diffusion tensor—both principal diffusion constants and orientation of the principal rotation axes—can be found by the measurement of the NMR relation times of an appropriate set of nuclei in the molecule.
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Dates
Type | When |
---|---|
Created | 21 years, 6 months ago (Feb. 4, 2004, 4:33 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 8, 2024, 10:41 p.m.) |
Indexed | 1 month, 4 weeks ago (July 1, 2025, 6:30 a.m.) |
Issued | 57 years, 4 months ago (April 15, 1968) |
Published | 57 years, 4 months ago (April 15, 1968) |
Published Print | 57 years, 4 months ago (April 15, 1968) |
@article{Huntress_1968, title={Effects of Anisotropic Molecular Rotational Diffusion on Nuclear Magnetic Relaxation in Liquids}, volume={48}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1669645}, DOI={10.1063/1.1669645}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Huntress, Wesley T.}, year={1968}, month=apr, pages={3524–3533} }