Abstract
The transition probabilities of the CO third positive (b 3Σ→a 3II), the CO Ångstrom (B 1Σ+→A 1II), and the CN violet (B 2Σ+→X 2Σ+) systems have been obtained from measurements of radiative lifetimes by the phase-shift method. In the CO Ångstrom system the probability of B 1Σ+→A 1II was distinguished from the (greater) probability for B 1Σ+→X 1Σ+ by taking advantage of reabsorption (or resonance trapping) of the shorter wavelength radiation. In the CN (B 2Σ+→X 2Σ+) transition there is found to be no measurable dependence of the electronic transition moment on internuclear distance.
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Dates
Type | When |
---|---|
Created | 21 years, 7 months ago (Feb. 4, 2004, 4:33 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 8, 2024, 10:48 p.m.) |
Indexed | 9 months, 2 weeks ago (Nov. 19, 2024, 10:50 a.m.) |
Issued | 57 years, 3 months ago (June 1, 1968) |
Published | 57 years, 3 months ago (June 1, 1968) |
Published Print | 57 years, 3 months ago (June 1, 1968) |
@article{Moore_1968, title={Study of Some Electronic Transition Probabilities in CO and CN}, volume={48}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1668096}, DOI={10.1063/1.1668096}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Moore, John H. and Robinson, Dean W.}, year={1968}, month=jun, pages={4870–4874} }