DOI: 10.1063/1.1661308. Electrode Polarization of Ionic Conductors

Electrode Polarization of Ionic Conductors

10.1063/1.1661308

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

Polarization observed on applying ac and dc electric fields to samples of β alumina, sodalime glass, and single crystals of sodium chloride have been studied. It is concluded that the large capacitances shown by these materials, which are generally attributed to space-charge effects, are more likely caused by reactions at the electrodes which build up cell potentials. Electrochemical models, involving these cell potential effects, are presented and compared with previous space-charge models which have been applied to solid electrolytes.

Bibliography

Mitoff, S. P., & Charles, R. J. (1972). Electrode Polarization of Ionic Conductors. Journal of Applied Physics, 43(3), 927â934.

Authors 2

S. P. Mitoff (first)
R. J. Charles (additional)

References 13 Referenced 74

10.1063/1.1740389 / J. Chem. Phys. (1954)
10.1063/1.1740390 / J. Chem. Phys. (1954)
10.1103/PhysRev.92.4 / Phys. Rev. (1953)
10.1063/1.1729876 / J. Chem. Phys. (1959)
10.1111/j.1151-2916.1960.tb12977.x / J. Am. Ceram. Soc. (1960)
10.1063/1.1740392 / J. Chem. Phys. (1954)
{'key': '2024020203483361600_r7'}
{'key': '2024020203483361600_r8'}
10.1016/0022-1902(67)80301-4 / J. Inorg. Nucl. Chem. (1967)
{'key': '2024020203483361600_r10'}
{'key': '2024020203483361600_r11', 'first-page': '747', 'volume': '13', 'year': '1940', 'journal-title': 'Acta Phys. Chim. URSS'} / Acta Phys. Chim. URSS (1940)
{'key': '2024020203483361600_r12', 'first-page': '125', 'volume': '6', 'year': '1901', 'journal-title': 'Ann. Phys.'} / Ann. Phys. (1901)
{'key': '2024020203483361600_r13', 'first-page': '37', 'volume': '60', 'year': '1956', 'journal-title': 'Z. Electrochem.'} / Z. Electrochem. (1956)

Dates

Type	When
Created	21 years, 6 months ago (Feb. 4, 2004, 12:25 p.m.)
Deposited	1 year, 6 months ago (Feb. 1, 2024, 10:48 p.m.)
Indexed	1 month, 1 week ago (July 22, 2025, 7:01 a.m.)
Issued	53 years, 5 months ago (March 1, 1972)
Published	53 years, 5 months ago (March 1, 1972)
Published Print	53 years, 5 months ago (March 1, 1972)

Funders 0

None

BibTeX

@article{Mitoff_1972, title={Electrode Polarization of Ionic Conductors}, volume={43}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1661308}, DOI={10.1063/1.1661308}, number={3}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Mitoff, S. P. and Charles, R. J.}, year={1972}, month=mar, pages={927–934} }

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