DOI: 10.1063/1.1659777. Mössbauer Line Positions and Hyperfine Interactions in α Iron

Mössbauer Line Positions and Hyperfine Interactions in α Iron

10.1063/1.1659777

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

The 57Fe Mössbauer spectrum of NBS standard reference material 1541 α-iron foil has been determined at 298±2 and 4.2±0.1°K, using a palladium source at 298±2°K. Line positions at 298 and 4.3°K were determined for the calibration of Mössbauer spectrometers. The magnetic splitting, in mm/sec, of the 57Fe ground state and first excited state are g0=(3.9098±0.0008), g1=(2.2342±0.0008) at 298°K and g0=(4.0117±0.0010), g1=(2.2931±0.0010) at 4.3°K. The center shift is − (0.1748±0.0008) mm/sec at 298°K and − (0.0556±0.0012) mm/sec at 4.3°K; the temperature shift is − (0.1192±0.0014) mm/sec. The hyperfine magnetic field is − (330.4±0.3) kOe at 298°K and − (339.0±0.3) kOe at 4.3°K. The 57Fe magnetic moment ratio is μ1/μ0=−1.7145±0.0005. The magnetic moment of the first excited state is μ1=−0.1547±0.0001 nm. The hyperfine magnetic field ratio is H(298°K)/H(4.3°K)=0.9746±0.0001. The electric quadrupole effect in terms of ε, the shift of the ±32 levels, is 4ε=+0.0023±0.0015 mm/sec at 298°K and 4ε=+0.0088±0.0025 mm/sec at 4.3°K. At 298°K, the quadrupole coupling is never between +0.0023±0.0015 mm/sec and −0.0046±0.0030 mm/sec. At 4.3°K, it is never between +0.0088±0.0025 mm/sec and −0.0176±0.0050 mm/sec. The 57Fe Mössbauer transition in palladium is more energetic than in sodium nitroprusside by 0.4361±0.0009 mm/sec.

Bibliography

Violet, C. E., & Pipkorn, D. N. (1971). MÃ¶ssbauer Line Positions and Hyperfine Interactions in Î± Iron. Journal of Applied Physics, 42(11), 4339â4342.

Authors 2

C. E. Violet (first)
D. N. Pipkorn (additional)

References 27 Referenced 82

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{'key': '2024020203261164300_r8'}
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Dates

Type	When
Created	21 years, 6 months ago (Feb. 9, 2004, 1:09 p.m.)
Deposited	1 year, 7 months ago (Feb. 1, 2024, 10:26 p.m.)
Indexed	1 year, 5 months ago (April 2, 2024, 12:38 a.m.)
Issued	53 years, 11 months ago (Oct. 1, 1971)
Published	53 years, 11 months ago (Oct. 1, 1971)
Published Print	53 years, 11 months ago (Oct. 1, 1971)

Funders 0

None

BibTeX

@article{Violet_1971, title={Mössbauer Line Positions and Hyperfine Interactions in α Iron}, volume={42}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1659777}, DOI={10.1063/1.1659777}, number={11}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Violet, C. E. and Pipkorn, D. N.}, year={1971}, month=oct, pages={4339–4342} }

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  "abstract": "<jats:p>The 57Fe M\u00f6ssbauer spectrum of NBS standard reference material 1541 \u03b1-iron foil has been determined at 298\u00b12 and 4.2\u00b10.1\u00b0K, using a palladium source at 298\u00b12\u00b0K. Line positions at 298 and 4.3\u00b0K were determined for the calibration of M\u00f6ssbauer spectrometers. The magnetic splitting, in mm/sec, of the 57Fe ground state and first excited state are g0=(3.9098\u00b10.0008), g1=(2.2342\u00b10.0008) at 298\u00b0K and g0=(4.0117\u00b10.0010), g1=(2.2931\u00b10.0010) at 4.3\u00b0K. The center shift is \u2212 (0.1748\u00b10.0008) mm/sec at 298\u00b0K and \u2212 (0.0556\u00b10.0012) mm/sec at 4.3\u00b0K; the temperature shift is \u2212 (0.1192\u00b10.0014) mm/sec. The hyperfine magnetic field is \u2212 (330.4\u00b10.3) kOe at 298\u00b0K and \u2212 (339.0\u00b10.3) kOe at 4.3\u00b0K. The 57Fe magnetic moment ratio is \u03bc1/\u03bc0=\u22121.7145\u00b10.0005. The magnetic moment of the first excited state is \u03bc1=\u22120.1547\u00b10.0001 nm. The hyperfine magnetic field ratio is H(298\u00b0K)/H(4.3\u00b0K)=0.9746\u00b10.0001. The electric quadrupole effect in terms of \u03b5, the shift of the \u00b132 levels, is 4\u03b5=+0.0023\u00b10.0015 mm/sec at 298\u00b0K and 4\u03b5=+0.0088\u00b10.0025 mm/sec at 4.3\u00b0K. At 298\u00b0K, the quadrupole coupling is never between +0.0023\u00b10.0015 mm/sec and \u22120.0046\u00b10.0030 mm/sec. At 4.3\u00b0K, it is never between +0.0088\u00b10.0025 mm/sec and \u22120.0176\u00b10.0050 mm/sec. The 57Fe M\u00f6ssbauer transition in palladium is more energetic than in sodium nitroprusside by 0.4361\u00b10.0009 mm/sec.</jats:p>",
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