DOI: 10.1063/1.1619935. Liquid–liquid demixing in a binary polymer blend driven solely by the component-selective crystallizability

Liquid–liquid demixing in a binary polymer blend driven solely by the component-selective crystallizability

10.1063/1.1619935

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

On the basis of an extended Flory–Huggins expression for the mixing free energy of the long-chain binary polymer blend, we showed that liquid–liquid demixing can be driven solely by the propensities of crystallization differing with respect to components. Demixing prior to crystallization on cooling was demonstrated by dynamic Monte Carlo simulations of the lattice model for a symmetric polymer blend where only one component is crystallizable. We discussed the implications of this principle to several experimental observations including the (in)compatibility of polymer chains with different stereochemical compositions, the memory effect of polymer crystallization, and the spinodal decomposition at an early stage of polymer crystallization.

Bibliography

Hu, W., & Mathot, V. B. F. (2003). Liquidâliquid demixing in a binary polymer blend driven solely by the component-selective crystallizability. The Journal of Chemical Physics, 119(20), 10953â10957.

Authors 2

Wenbing Hu (first)
Vincent B. F. Mathot (additional)

References 45 Referenced 27

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Dates

Type	When
Created	21 years, 8 months ago (Dec. 3, 2003, 2:29 p.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 11:22 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 11:40 a.m.)
Issued	21 years, 9 months ago (Nov. 22, 2003)
Published	21 years, 9 months ago (Nov. 22, 2003)
Published Print	21 years, 9 months ago (Nov. 22, 2003)

Funders 0

None

BibTeX

@article{Hu_2003, title={Liquid–liquid demixing in a binary polymer blend driven solely by the component-selective crystallizability}, volume={119}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1619935}, DOI={10.1063/1.1619935}, number={20}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hu, Wenbing and Mathot, Vincent B. F.}, year={2003}, month=nov, pages={10953–10957} }

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