DOI: 10.1063/1.1532349. Stokes–Einstein relations and the fluctuation-dissipation theorem in a supercooled colloidal fluid

Stokes–Einstein relations and the fluctuation-dissipation theorem in a supercooled colloidal fluid

10.1063/1.1532349

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The Stokes–Einstein (SE) relation is a form of the fluctuation-dissipation theorem (FDT), and relates the diffusion coefficient of colloidal particles to the viscosity via the thermal energy kBT. We study the diffusion coefficient and viscosity of concentrated hard-sphere colloidal model systems in the frequency domain. We show that for these metastable fluid systems strong deviations from the SE relation occur, contrary to predictions of mode coupling theory. Using the FDT, these deviations can be quantified by an effective temperature, Teff. The deviation Teff/T−1 exhibits power-law behavior over several decades in frequency.

Bibliography

Bonn, D., & Kegel, W. K. (2003). StokesâEinstein relations and the fluctuation-dissipation theorem in a supercooled colloidal fluid. The Journal of Chemical Physics, 118(4), 2005â2009.

Authors 2

Daniel Bonn (first)
Willem K. Kegel (additional)

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Dates

Type	When
Created	22 years, 7 months ago (Jan. 9, 2003, 11:40 a.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 11:47 a.m.)
Indexed	1 year, 5 months ago (Feb. 24, 2024, 11:46 a.m.)
Issued	22 years, 7 months ago (Jan. 22, 2003)
Published	22 years, 7 months ago (Jan. 22, 2003)
Published Print	22 years, 7 months ago (Jan. 22, 2003)

Funders 0

None

BibTeX

@article{Bonn_2003, title={Stokes–Einstein relations and the fluctuation-dissipation theorem in a supercooled colloidal fluid}, volume={118}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1532349}, DOI={10.1063/1.1532349}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Bonn, Daniel and Kegel, Willem K.}, year={2003}, month=jan, pages={2005–2009} }

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