DOI: 10.1063/1.1435415. Phase transitions and dielectric properties in A-site ion substituted (Na1/2Bi1/2)TiO3 ceramics (A=Pb and Sr)

Phase transitions and dielectric properties in A-site ion substituted (Na1/2Bi1/2)TiO3 ceramics (A=Pb and Sr)

10.1063/1.1435415

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

The dielectric permittivity of A-site ion substituted (Na1/2Bi1/2)TiO3(A=Pb,Sr) solid solutions has been investigated with the aid of structural analysis. As the addition of PT increased, the first order characteristics of the phase transition appeared. In contrast, additions of ST made the solid solution exhibit relaxor ferroelectrics behavior. Microscopic structural analysis revealed that the dielectric properties were determined by cation ordering which controlled the translational symmetry and domain configuration. In the NBT–PT solid solution, A-site cations were randomly redistributed and macrodomains formed. However, the addition of ST distributed A-site cations with local ordering and divided the domains of NBT into micropolar regions. The contrasting effects of the addition of the Pb and Sr cations on the dielectric properties of NBT are discussed in terms of the polarizability and the tolerance factors as they relate to the perovskite structure.

Bibliography

Lee, J.-K., Hong, K. S., Kim, C. K., & Park, S.-E. (2002). Phase transitions and dielectric properties in A-site ion substituted (Na1/2Bi1/2)TiO3 ceramics (A=Pb and Sr). Journal of Applied Physics, 91(7), 4538â4542.

Authors 4

Jung-Kun Lee (first)
Kug Sun Hong (additional)
Chang Kyung Kim (additional)
Seung-Eek Park (additional)

References 23 Referenced 105

{'key': '2024020709054085500_r1', 'first-page': '2651', 'volume': '2', 'year': '1961', 'journal-title': 'Sov. Phys. Solid State'} / Sov. Phys. Solid State (1961)
10.1080/00150198208210600 / Ferroelectrics (1982)
10.1111/j.1151-2916.1996.tb08586.x / J. Am. Ceram. Soc. (1996)
10.1080/00150198808223232 / Ferroelectrics (1988)
{'key': '2024020709054085500_r5', 'first-page': '482', 'volume': '26', 'year': '1981', 'journal-title': 'Sov. Phys. Crystallogr.'} / Sov. Phys. Crystallogr. (1981)
10.1103/PhysRevB.49.11550 / Phys. Rev. B (1994)
10.1557/JMR.1997.0288 / J. Mater. Res. (1997)
10.1063/1.360842 / J. Appl. Phys. (1996)
10.1080/00150197408238042 / Ferroelectrics (1974)
{'key': '2024020709054085500_r10', 'first-page': '1429', 'volume': '1', 'year': '1960', 'journal-title': 'Sov. Phys. Solid State'} / Sov. Phys. Solid State (1960)
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{'key': '2024020709054085500_r13', 'first-page': '483', 'volume': '16', 'year': '1984', 'journal-title': 'J. Phys. C'} / J. Phys. C (1984)
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{'key': '2024020709054085500_r17'}
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Dates

Type	When
Created	23 years ago (July 26, 2002, 9:27 a.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 9:50 a.m.)
Indexed	7 months, 3 weeks ago (Dec. 30, 2024, 1:07 p.m.)
Issued	23 years, 4 months ago (April 1, 2002)
Published	23 years, 4 months ago (April 1, 2002)
Published Print	23 years, 4 months ago (April 1, 2002)

Funders 0

None

BibTeX

@article{Lee_2002, title={Phase transitions and dielectric properties in A-site ion substituted (Na1/2Bi1/2)TiO3 ceramics (A=Pb and Sr)}, volume={91}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1435415}, DOI={10.1063/1.1435415}, number={7}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Lee, Jung-Kun and Hong, Kug Sun and Kim, Chang Kyung and Park, Seung-Eek}, year={2002}, month=apr, pages={4538–4542} }

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