Abstract
We report on the effects of partial substitution of nickel by palladium on the thermoelectric properties of ZrNiSn-based half-Heusler compounds. It is shown that the substitution of palladium for nickel results in a significant, beneficial reduction of the thermal conductivity. The Seebeck coefficient also decreases, but only by a small amount. In the Hf0.5Zr0.5Ni0.8Pd0.2Sn0.99Sb0.01 compound, a power factor of 22.1 μW K−2 cm−1 and a thermal conductivity as low as 4.5 W/m K are measured at room temperature. The dimensionless figure of merit ZT increases with increasing temperature and reaches a maximum value of 0.7 at about 800 K.
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Dates
Type | When |
---|---|
Created | 23 years, 1 month ago (July 26, 2002, 9:15 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 3, 2024, 4:18 p.m.) |
Indexed | 5 days, 21 hours ago (Aug. 23, 2025, 12:58 a.m.) |
Issued | 23 years, 8 months ago (Dec. 17, 2001) |
Published | 23 years, 8 months ago (Dec. 17, 2001) |
Published Print | 23 years, 8 months ago (Dec. 17, 2001) |
@article{Shen_2001, title={Effects of partial substitution of Ni by Pd on the thermoelectric properties of ZrNiSn-based half-Heusler compounds}, volume={79}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.1425459}, DOI={10.1063/1.1425459}, number={25}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Shen, Q. and Chen, L. and Goto, T. and Hirai, T. and Yang, J. and Meisner, G. P. and Uher, C.}, year={2001}, month=dec, pages={4165–4167} }