Abstract
We have used oxygen-plasma-assisted molecular-beam epitaxy (OPA-MBE) to grow CoxTi1−xO2 anatase on SrTiO3(001) for x=∼0.01–0.10, and have measured the structural, compositional, and magnetic properties of the resulting films. Whether epitaxial or polycrystalline, these CoxTi1−xO2 films are ferromagnetic semiconductors at and above room temperature. However, the magnetic and structural properties depend critically on the Co distribution, which varies widely with growth conditions. Co is substitutional in the anatase lattice and in the +2 formal oxidation state in ferromagnetic CoxTi1−xO2. The magnetic properties of OPA-MBE grown material are significantly better than those of analogous pulsed laser deposition-grown material.
Bibliography
Chambers, S. A., Thevuthasan, S., Farrow, R. F. C., Marks, R. F., Thiele, J. U., Folks, L., Samant, M. G., Kellock, A. J., Ruzycki, N., Ederer, D. L., & Diebold, U. (2001). Epitaxial growth and properties of ferromagnetic co-doped TiO2 anatase. Applied Physics Letters, 79(21), 3467â3469.
References
10
Referenced
374
10.12693/APhysPolA.98.203
/ Acta Phys. Pol. A (2000)10.1038/45502
/ Nature (London) (1999)10.1103/PhysRevB.62.8180
/ Phys. Rev. B (2000)10.1126/science.1056186
/ Science (2001)10.1016/S0167-5729(00)00005-4
/ Surf. Sci. Rep. (2000)10.1116/1.578587
/ J. Vac. Sci. Technol. A (1993){'key': '2024020321092581300_r7', 'first-page': '235402', 'volume': '63', 'year': '2000', 'journal-title': 'Phys. Rev. B'}
/ Phys. Rev. B (2000)10.1063/1.1365412
/ Appl. Phys. Lett. (2001)10.1143/PTP.23.1055
/ Prog. Theor. Phys. (1960){'key': '2024020321092581300_r10'}
Dates
Type | When |
---|---|
Created | 23 years, 1 month ago (July 26, 2002, 9:59 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 3, 2024, 4:09 p.m.) |
Indexed | 3 months, 1 week ago (May 15, 2025, 9:06 a.m.) |
Issued | 23 years, 9 months ago (Nov. 19, 2001) |
Published | 23 years, 9 months ago (Nov. 19, 2001) |
Published Print | 23 years, 9 months ago (Nov. 19, 2001) |
@article{Chambers_2001, title={Epitaxial growth and properties of ferromagnetic co-doped TiO2 anatase}, volume={79}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.1420434}, DOI={10.1063/1.1420434}, number={21}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Chambers, S. A. and Thevuthasan, S. and Farrow, R. F. C. and Marks, R. F. and Thiele, J. U. and Folks, L. and Samant, M. G. and Kellock, A. J. and Ruzycki, N. and Ederer, D. L. and Diebold, U.}, year={2001}, month=nov, pages={3467–3469} }