DOI: 10.1063/1.1419263. Role of metal–molecule chemistry and interdiffusion on the electrical properties of an organic interface: The Al

Role of metal–molecule chemistry and interdiffusion on the electrical properties of an organic interface: The Al–F16CuPc case

10.1063/1.1419263

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

The chemistry and electronic structure of interfaces between Al and copper hexadecafluorophthalocyanine (F16CuPc) are studied via x-ray photoemission spectroscopy, ultraviolet photoemission spectroscopy (UPS), and current–voltage measurements. Electron injection barriers measured by UPS are reported. Analysis of the Al–F16CuPc reaction shows the formation of a phase of three-dimensional (F16CuPc)3Al species. The reacted region is extended at the Al-on-F16CuPc interface and narrow at the F16CuPc-on-Al interface. A series of metal/F16CuPc/metal structures is fabricated to study the impact of the interface chemistry and deposition sequence on device performances. It is found that (F16CuPc)3Al forms a low conductivity region, which has considerable bearing on the electron current. The interface fabrication sequence, which defines the thickness of the reacted region, therefore has a profound impact on device performance.

Bibliography

Shen, C., Kahn, A., & Schwartz, J. (2001). Role of metalâmolecule chemistry and interdiffusion on the electrical properties of an organic interface: The AlâF16CuPc case. Journal of Applied Physics, 90(12), 6236â6242.

Authors 3

Chongfei Shen (first)
Antoine Kahn (additional)
Jeffrey Schwartz (additional)

References 13 Referenced 48

10.1021/ja994265t / J. Am. Chem. Soc. (2000)
10.1016/S1566-1199(01)00015-5 / Org. Electron. (2001)
10.1063/1.1333740 / J. Appl. Phys. (2001)
10.1063/1.1406967 / J. Appl. Phys. (2001)
10.1021/ja9727629 / J. Am. Chem. Soc. (1998)
10.1002/(SICI)1521-4095(200002)12:3<227::AID-ADMA227>3.0.CO;2-U / Adv. Mater. (2000)
10.1002/(SICI)1521-4095(199912)11:18<1523::AID-ADMA1523>3.0.CO;2-K / Adv. Mater. (1999)
{'key': '2024020620333409000_r8'}
{'key': '2024020620333409000_r9', 'first-page': '518', 'volume': '402–404', 'year': '1998', 'journal-title': 'Surf. Sci.'} / Surf. Sci. (1998)
{'key': '2024020620333409000_r10', 'first-page': '355', 'volume': '13', 'year': '1997', 'journal-title': 'Anal. Sci.'} / Anal. Sci. (1997)
10.1063/1.440166 / J. Phys. Chem. (1980)
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:01 a.m.)
Deposited	1 year, 6 months ago (Feb. 6, 2024, 7:17 p.m.)
Indexed	1 year, 1 month ago (July 5, 2024, 5:17 p.m.)
Issued	23 years, 8 months ago (Dec. 15, 2001)
Published	23 years, 8 months ago (Dec. 15, 2001)
Published Print	23 years, 8 months ago (Dec. 15, 2001)

Funders 0

None

BibTeX

@article{Shen_2001, title={Role of metal–molecule chemistry and interdiffusion on the electrical properties of an organic interface: The Al–F16CuPc case}, volume={90}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1419263}, DOI={10.1063/1.1419263}, number={12}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Shen, Chongfei and Kahn, Antoine and Schwartz, Jeffrey}, year={2001}, month=dec, pages={6236–6242} }

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