Crossref journal-article
AIP Publishing
Journal of Applied Physics (317)
Abstract

We report on the temperature dependence of various photovoltaic device parameters of solar cells, fabricated from interpenetrating networks of conjugated polymers with fullerenes, in the wide temperature range of their possible operating conditions (25–60 °C). The open-circuit voltage was found to decrease linearly with increasing temperature. For the short-circuit current, we observed a monotonic increase with increasing temperature, followed by a saturation region. The rate of this increase (coupled to a corresponding increase for the fill factor) was found to overtake the corresponding rate of decrease in voltage, resulting in an overall increase of the energy conversion efficiency. The efficiency was observed to reach a maximum value in the approximate range 47–60 °C. The results are discussed with respect to possible mechanisms for photovoltage generation and charge carrier transport in the conjugated polymer-fullerene composite, and in particular, thermally activated charge carrier mobility.

Bibliography

Katz, E. A., Faiman, D., Tuladhar, S. M., Kroon, J. M., Wienk, M. M., Fromherz, T., Padinger, F., Brabec, C. J., & Sariciftci, N. S. (2001). Temperature dependence for the photovoltaic device parameters of polymer-fullerene solar cells under operating conditions. Journal of Applied Physics, 90(10), 5343–5350.

Authors 9
  1. E. A. Katz (first)
  2. D. Faiman (additional)
  3. S. M. Tuladhar (additional)
  4. J. M. Kroon (additional)
  5. M. M. Wienk (additional)
  6. T. Fromherz (additional)
  7. F. Padinger (additional)
  8. C. J. Brabec (additional)
  9. N. S. Sariciftci (additional)
References 46 Referenced 176
  1. {'key': '2024021015550108500_r1'}
  2. {'key': '2024021015550108500_r2'}
  3. 10.1063/1.96937 / Appl. Phys. Lett. (1986)
  4. 10.1002/adma.19910030303 / Adv. Mater. (1991)
  5. 10.1038/376498a0 / Nature (London) (1995)
  6. 10.1038/26183 / Nature (London) (1998)
  7. 10.1063/1.126433 / Appl. Phys. Lett. (2000)
  8. 10.1038/35000172 / Nature (London) (2000)
  9. 10.1063/1.108863 / Appl. Phys. Lett. (1993)
  10. 10.1126/science.270.5243.1789 / Science (1995)
  11. 10.1063/1.370205 / J. Appl. Phys. (1999)
  12. 10.1016/S0379-6779(00)00276-9 / Synth. Met. (2001)
  13. {'key': '2024021015550108500_r13'}
  14. 10.1126/science.258.5087.1474 / Science (1992)
  15. 10.1103/PhysRevB.47.13835 / Phys. Rev. B (1993)
  16. {'key': '2024021015550108500_r16'}
  17. 10.1063/1.1345834 / Appl. Phys. Lett. (2001)
  18. {'key': '2024021015550108500_r18', 'first-page': '87', 'volume': '21', 'year': '2000', 'journal-title': 'Sol. Energy Mater. Sol. Cells'} / Sol. Energy Mater. Sol. Cells (2000)
  19. 10.1016/0927-0248(94)00198-7 / Sol. Energy Mater. Sol. Cells (1995)
  20. 10.1016/S0927-0248(96)00087-6 / Sol. Energy Mater. Sol. Cells (1997)
  21. 10.1021/jp9532071 / J. Phys. Chem. (1996)
  22. 10.1021/jo00108a012 / J. Org. Chem. (1995)
  23. 10.1063/1.122367 / Appl. Phys. Lett. (1998)
  24. 10.1063/1.118344 / Appl. Phys. Lett. (1997)
  25. 10.1016/S0927-0248(00)00020-9 / Sol. Energy Mater. Sol. Cells (2000)
  26. 10.1016/S0927-0248(00)00004-0 / Sol. Energy Mater. Sol. Cells (2000)
  27. {'key': '2024021015550108500_r27'}
  28. {'key': '2024021015550108500_r28'}
  29. {'key': '2024021015550108500_r29'}
  30. 10.1063/1.356350 / J. Appl. Phys. (1994)
  31. 10.1063/1.359792 / J. Appl. Phys. (1995)
  32. 10.1063/1.111885 / Appl. Phys. Lett. (1994)
  33. {'key': '2024021015550108500_r33'}
  34. 10.1117/12.416940 / Proc. SPIE (2001)
  35. {'key': '2024021015550108500_r35', 'first-page': '145', 'volume': '2', 'year': '1982', 'journal-title': 'Surf. Sci. Rep.'} / Surf. Sci. Rep. (1982)
  36. {'key': '2024021015550108500_r36'}
  37. 10.1016/S0927-0248(99)00094-X / Sol. Energy Mater. Sol. Cells (2000)
  38. {'key': '2024021015550108500_r38', 'first-page': '121', 'volume': '1517–1521', 'year': '2001', 'journal-title': 'Synth. Met.'} / Synth. Met. (2001)
  39. 10.1016/S0927-796X(00)00009-7 / Mater. Sci. Eng., R. (2000)
  40. 10.1016/S0927-0248(98)00114-7 / Sol. Energy Mater. Sol. Cells (1998)
  41. 10.1016/S0040-6090(99)00951-7 / Thin Solid Films (2000)
  42. 10.1080/10587259308032183 / Mol. Cryst. Liq. Cryst. (1993)
  43. {'key': '2024021015550108500_r43'}
  44. 10.1002/1521-4095(200007)12:14<1046::AID-ADMA1046>3.0.CO;2-W / Adv. Mater. (2000)
  45. 10.1126/science.287.5455.1022 / Science (2000)
  46. {'key': '2024021015550108500_r46'}
Dates
Type When
Created 23 years ago (July 26, 2002, 8:41 a.m.)
Deposited 1 year, 6 months ago (Feb. 10, 2024, 11:53 a.m.)
Indexed 2 months, 3 weeks ago (May 28, 2025, 12:26 a.m.)
Issued 23 years, 9 months ago (Nov. 15, 2001)
Published 23 years, 9 months ago (Nov. 15, 2001)
Published Print 23 years, 9 months ago (Nov. 15, 2001)
Funders 0

None

@article{Katz_2001, title={Temperature dependence for the photovoltaic device parameters of polymer-fullerene solar cells under operating conditions}, volume={90}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1412270}, DOI={10.1063/1.1412270}, number={10}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Katz, E. A. and Faiman, D. and Tuladhar, S. M. and Kroon, J. M. and Wienk, M. M. and Fromherz, T. and Padinger, F. and Brabec, C. J. and Sariciftci, N. S.}, year={2001}, month=nov, pages={5343–5350} }