DOI: 10.1063/1.1410116. Time-resolved fluorescence of polarizable chromophores

Time-resolved fluorescence of polarizable chromophores

10.1063/1.1410116

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The paper reports an exact solution for spectral profiles of time-resolved fluorescence following a broad-band excitation producing changes in both the chromophore’s dipole moment and the polarizability. The problem is formulated in terms of a two-state chromophore with a bilinear coupling to a Gaussian solvent mode. Closed-form solutions for the time-dependent spectral shift and width are obtained. These two transient spectral moments are sufficient to generate transient, non-Gaussian band-shapes by using the proposed formalism. An approximately linear relation between the normalized shift and width time correlation functions is found. The Stokes shift correlation function is virtually insensitive to the nonlinear solute–solvent effects, in spite of dramatic transient changes in the spectral width. Depending on chromophore’s parameters, the transient line shape can be well approximated by a nonstationary Gaussian process or shows clearly non-Gaussian statistics. The model is extended to treat heterogeneous solvent dynamics.

Bibliography

Matyushov, D. V. (2001). Time-resolved fluorescence of polarizable chromophores. The Journal of Chemical Physics, 115(19), 8933â8941.

Authors 1

Dmitry V. Matyushov (first)

References 48 Referenced 23

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:42 a.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 3:27 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 2:21 p.m.)
Issued	23 years, 9 months ago (Nov. 15, 2001)
Published	23 years, 9 months ago (Nov. 15, 2001)
Published Print	23 years, 9 months ago (Nov. 15, 2001)

Funders 0

None

BibTeX

@article{Matyushov_2001, title={Time-resolved fluorescence of polarizable chromophores}, volume={115}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1410116}, DOI={10.1063/1.1410116}, number={19}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Matyushov, Dmitry V.}, year={2001}, month=nov, pages={8933–8941} }

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