DOI: 10.1063/1.1407290. Liquid-to-crystal nucleation: Automated lag-time apparatus to study supercooled liquids

Liquid-to-crystal nucleation: Automated lag-time apparatus to study supercooled liquids

10.1063/1.1407290

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The statistics of liquid-to-crystal nucleation are studied using an automated lag-time apparatus. A single 500 μL sample of distilled water is repeatedly supercooled to a fixed temperature below its equilibrium freezing temperature, held until freezing occurred, and then thawed. Our raw data is then a set of approximately 300 lag-times for each of three set supercooling temperatures. In each case, a small insoluble AgI crystal was added to ensure heterogeneous nucleation and average nucleation temperatures around ΔT=8 K. The distribution of lag-times is analyzed, and shown to be well approximated by a single exponential decay, with average lag-times in the range of 1000–3000 seconds. This average lag-time decreases markedly at deeper levels of supercooling, and for the present data, this decrease is fit equally well by exponential, power law decay, and classical nucleation functional forms.

Bibliography

Heneghan, A. F., Wilson, P. W., Wang, G., & Haymet, A. D. J. (2001). Liquid-to-crystal nucleation: Automated lag-time apparatus to study supercooled liquids. The Journal of Chemical Physics, 115(16), 7599â7608.

Authors 4

A. F. Heneghan (first)
P. W. Wilson (additional)
Genmiao Wang (additional)
A. D. J. Haymet (additional)

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Dates

Type	When
Created	23 years ago (July 26, 2002, 8:45 a.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 1:23 p.m.)
Indexed	3 weeks, 5 days ago (July 30, 2025, 9:55 a.m.)
Issued	23 years, 10 months ago (Oct. 22, 2001)
Published	23 years, 10 months ago (Oct. 22, 2001)
Published Print	23 years, 10 months ago (Oct. 22, 2001)

Funders 0

None

BibTeX

@article{Heneghan_2001, title={Liquid-to-crystal nucleation: Automated lag-time apparatus to study supercooled liquids}, volume={115}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1407290}, DOI={10.1063/1.1407290}, number={16}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Heneghan, A. F. and Wilson, P. W. and Wang, Genmiao and Haymet, A. D. J.}, year={2001}, month=oct, pages={7599–7608} }

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