DOI: 10.1063/1.1398605. Vitrification and determination of the crystallization time scales of the bulk-metallic-glass-forming liquid Zr58.5Nb2.8Cu15.6Ni12.8Al10.3

Vitrification and determination of the crystallization time scales of the bulk-metallic-glass-forming liquid Zr58.5Nb2.8Cu15.6Ni12.8Al10.3

10.1063/1.1398605

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

The crystallization kinetics of Zr58.5Nb2.8Cu15.6Ni12.8Al10.3 were studied in an electrostatic levitation (ESL) apparatus. The measured critical cooling rate is 1.75 K/s. Zr58.5Nb2.8Cu15.6Ni12.8Al10.3 is the first bulk-metallic-glass-forming liquid that does not contain beryllium to be vitrified by purely radiative cooling in the ESL. Furthermore, the sluggish crystallization kinetics enable the determination of the time-temperature-transformation (TTT) diagram between the liquidus and the glass transition temperatures. The shortest time to reach crystallization in an isothermal experiment; i.e., the nose of the TTT diagram is 32 s. The nose of the TTT diagram is at 900 K and positioned about 200 K below the liquidus temperature.

Bibliography

Hays, C. C., Schroers, J., Johnson, W. L., Rathz, T. J., Hyers, R. W., Rogers, J. R., & Robinson, M. B. (2001). Vitrification and determination of the crystallization time scales of the bulk-metallic-glass-forming liquid Zr58.5Nb2.8Cu15.6Ni12.8Al10.3. Applied Physics Letters, 79(11), 1605â1607.

Authors 7

C. C. Hays (first)
J. Schroers (additional)
W. L. Johnson (additional)
T. J. Rathz (additional)
R. W. Hyers (additional)
J. R. Rogers (additional)
M. B. Robinson (additional)

References 16 Referenced 80

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{'key': '2024020320441801900_r3'}
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10.1016/S1359-6454(98)00242-0 / Acta Mater. (1998)
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{'key': '2024020320441801900_r10'}
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 10:16 a.m.)
Deposited	1 year, 7 months ago (Feb. 3, 2024, 3:44 p.m.)
Indexed	1 month ago (Aug. 3, 2025, 12:24 a.m.)
Issued	23 years, 11 months ago (Sept. 10, 2001)
Published	23 years, 11 months ago (Sept. 10, 2001)
Published Print	23 years, 11 months ago (Sept. 10, 2001)

Funders 0

None

BibTeX

@article{Hays_2001, title={Vitrification and determination of the crystallization time scales of the bulk-metallic-glass-forming liquid Zr58.5Nb2.8Cu15.6Ni12.8Al10.3}, volume={79}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.1398605}, DOI={10.1063/1.1398605}, number={11}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Hays, C. C. and Schroers, J. and Johnson, W. L. and Rathz, T. J. and Hyers, R. W. and Rogers, J. R. and Robinson, M. B.}, year={2001}, month=sep, pages={1605–1607} }

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