DOI: 10.1063/1.1386433. Theory of ultrafast photoinduced heterogeneous electron transfer: Decay of vibrational coherence into a finite electronic

Theory of ultrafast photoinduced heterogeneous electron transfer: Decay of vibrational coherence into a finite electronic–vibrational quasicontinuum

10.1063/1.1386433

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Photo-induced electron transfer from a surface attached dye molecule to the band levels of a semiconductor is modeled via an electronic–vibronic quasicontinuum. The description enables one to obtain a fairly accurate expression for the decay of the excited molecular state, including initial vibronic coherences. The model accounts for (a) the effect of a finite band width, (b) variations in reorganization energy and electronic coupling, (c) various energetic positions for the injecting level, (d) different initial vibrational wave packets in the excited state, and (e) two vibrational modes participating in the electron transfer process. Most cases are studied numerically and can be reasonably well understood from the obtained decay expression.

Bibliography

Ramakrishna, S., Willig, F., & May, V. (2001). Theory of ultrafast photoinduced heterogeneous electron transfer: Decay of vibrational coherence into a finite electronicâvibrational quasicontinuum. The Journal of Chemical Physics, 115(6), 2743â2756.

Authors 3

S. Ramakrishna (first)
F. Willig (additional)
V. May (additional)

References 45 Referenced 74

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:44 a.m.)
Deposited	1 year, 6 months ago (Feb. 6, 2024, 6:55 p.m.)
Indexed	1 year, 2 months ago (May 30, 2024, 9:53 a.m.)
Issued	24 years ago (Aug. 8, 2001)
Published	24 years ago (Aug. 8, 2001)
Published Print	24 years ago (Aug. 8, 2001)

Funders 0

None

BibTeX

@article{Ramakrishna_2001, title={Theory of ultrafast photoinduced heterogeneous electron transfer: Decay of vibrational coherence into a finite electronic–vibrational quasicontinuum}, volume={115}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1386433}, DOI={10.1063/1.1386433}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Ramakrishna, S. and Willig, F. and May, V.}, year={2001}, month=aug, pages={2743–2756} }

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