DOI: 10.1063/1.1385362. Hydrogen desorption property of mechanically prepared nanostructured graphite

Hydrogen desorption property of mechanically prepared nanostructured graphite

10.1063/1.1385362

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

Two desorption peaks of hydrogen molecule (mass number=2), starting at about 600 and 950 K, respectively, are observed in thermal desorption mass spectroscopy of nanostructured graphite mechanically milled for 80 h under hydrogen atmosphere. It follows from a combined analysis of thermal desorption mass spectroscopy and thermogravimetry, that ∼6 mass % of hydrogen (corresponding to 80% of the total amount of hydrogen) is desorbed at the first desorption peak as a mixture of pure hydrogen and hydrocarbons. Below the temperature of the second desorption peak, at which recrystallization related desorption occurs, nanostructured graphite is expected to retain its specific defective structures mainly with carbon dangling bonds as suitable trapping sites for hydrogen storage. The formation process of the nanostructures during milling under hydrogen atmosphere is also discussed on the basis of the profile of Raman spectroscopy.

Bibliography

Orimo, S., Matsushima, T., Fujii, H., Fukunaga, T., & Majer, G. (2001). Hydrogen desorption property of mechanically prepared nanostructured graphite. Journal of Applied Physics, 90(3), 1545â1549.

Authors 5

S. Orimo (first)
T. Matsushima (additional)
H. Fujii (additional)
T. Fukunaga (additional)
G. Majer (additional)

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Dates

Type	When
Created	23 years ago (July 26, 2002, 8:44 a.m.)
Deposited	1 year, 6 months ago (Feb. 6, 2024, 5:37 a.m.)
Indexed	1 month ago (July 19, 2025, 11:34 p.m.)
Issued	24 years ago (Aug. 1, 2001)
Published	24 years ago (Aug. 1, 2001)
Published Print	24 years ago (Aug. 1, 2001)

Funders 0

None

BibTeX

@article{Orimo_2001, title={Hydrogen desorption property of mechanically prepared nanostructured graphite}, volume={90}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1385362}, DOI={10.1063/1.1385362}, number={3}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Orimo, S. and Matsushima, T. and Fujii, H. and Fukunaga, T. and Majer, G.}, year={2001}, month=aug, pages={1545–1549} }

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