DOI: 10.1063/1.1384475. Universal phase diagram for high-piezoelectric perovskite systems

Universal phase diagram for high-piezoelectric perovskite systems

10.1063/1.1384475

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

Strong piezoelectricity in perovskite-type PbZn1−xTixO3 (PZT) and Pb(Zn1/3Nb2/3)O3–PbTiO3 (PZN–PT) systems is generally associated with the existence of a morphotropic phase boundary (MPB) separating regions with rhombohedral and tetragonal symmetry. An x-ray study of PZN–9% PT has revealed the presence of an orthorhombic phase at the MPB, and a near-vertical boundary between the rhombohedral and orthorhombic phases, similar to that found for PZT between the rhombohedral and monoclinic phases. We discuss the results in the light of a recent theoretical paper by Vanderbilt and Cohen [Phys. Rev. B 63, 94108 (2001)], which attributes these low-symmetry phases to the high anharmonicity in these oxide systems.

Bibliography

Cox, D. E., Noheda, B., Shirane, G., Uesu, Y., Fujishiro, K., & Yamada, Y. (2001). Universal phase diagram for high-piezoelectric perovskite systems. Applied Physics Letters, 79(3), 400â402.

Authors 6

D. E. Cox (first)
B. Noheda (additional)
G. Shirane (additional)
Y. Uesu (additional)
K. Fujishiro (additional)
Y. Yamada (additional)

References 17 Referenced 285

10.1063/1.365983 / J. Appl. Phys. (1997)
10.1126/science.275.5308.1878 / Science (1997)
10.1063/1.123756 / Appl. Phys. Lett. (1999)
10.1103/PhysRevB.61.8687 / Phys. Rev. B (2000)
10.1103/PhysRevLett.84.5423 / Phys. Rev. Lett. (2000)
10.1103/PhysRevLett.84.5427 / Phys. Rev. Lett. (2000)
{'key': '2024020320280829000_r7', 'first-page': '014103', 'volume': '63', 'year': '2001', 'journal-title': 'Phys. Rev. B'} / Phys. Rev. B (2001)
{'key': '2024020320280829000_r8'}
10.1080/00150198108223490 / Ferroelectrics (1981)
10.1103/PhysRevLett.86.3891 / Phys. Rev. Lett. (2001)
10.1143/JJAP.37.5246 / Jpn. J. Appl. Phys., Part 1 (1998)
10.1143/JJAP.35.3984 / Jpn. J. Appl. Phys., Part 1 (1996)
{'key': '2024020320280829000_r13'}
10.1080/00150199808015052 / Ferroelectrics (1998)
10.1103/PhysRevB.63.094108 / Phys. Rev. B (2001)
{'key': '2024020320280829000_r16', 'first-page': '86', 'volume': '3', 'year': '1954', 'journal-title': 'Adv. Phys.'} / Adv. Phys. (1954)
10.1038/35002022 / Nature (London) (2000)

Dates

Type	When
Created	23 years ago (July 26, 2002, 8:44 a.m.)
Deposited	1 year, 6 months ago (Feb. 3, 2024, 3:28 p.m.)
Indexed	2 weeks, 3 days ago (Aug. 5, 2025, 8:16 a.m.)
Issued	24 years, 1 month ago (July 16, 2001)
Published	24 years, 1 month ago (July 16, 2001)
Published Print	24 years, 1 month ago (July 16, 2001)

Funders 0

None

BibTeX

@article{Cox_2001, title={Universal phase diagram for high-piezoelectric perovskite systems}, volume={79}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.1384475}, DOI={10.1063/1.1384475}, number={3}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Cox, D. E. and Noheda, B. and Shirane, G. and Uesu, Y. and Fujishiro, K. and Yamada, Y.}, year={2001}, month=jul, pages={400–402} }

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