Abstract
Neutron diffraction experiments were carried out on a mixture of argon in water under a pressure of 300 bar and a temperature of 318 °C. The data were analyzed by standard procedures and showed that the argon atom is hydrated with 9 (1) water molecules, a substantial reduction from the value of 16 (2) at ambient temperature and a pressure of 250 bar. This result is in excellent agreement with the computer simulation study of Guissani and Guillot, which was carried out on an argon/water mixture at high temperatures and pressures.
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Dates
Type | When |
---|---|
Created | 23 years ago (July 26, 2002, 10:18 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 7, 2024, 7:08 a.m.) |
Indexed | 4 months, 2 weeks ago (April 8, 2025, 4:22 a.m.) |
Issued | 24 years, 1 month ago (July 1, 2001) |
Published | 24 years, 1 month ago (July 1, 2001) |
Published Print | 24 years, 1 month ago (July 1, 2001) |
@article{Sullivan_2001, title={Hydrophobic hydration of argon at high temperatures}, volume={115}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1376649}, DOI={10.1063/1.1376649}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Sullivan, D. M. and Neilson, G. W. and Fischer, H. E.}, year={2001}, month=jul, pages={339–343} }