DOI: 10.1063/1.1369399. Micro-Raman scattering and dielectric investigations of phase transition behavior in the BaTiO3

Micro-Raman scattering and dielectric investigations of phase transition behavior in the BaTiO3–BaZrO3 system

10.1063/1.1369399

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

In this study, the phase transition behavior of the BaTiO3–BaZrO3 system was studied using micro-Raman scattering and dielectric measurement techniques. BaZrxTi1−xO3 ceramics were prepared for x=0.00, 0.05, 0.08, 0.15, 0.20, and 1.00 compositions using a solid-state reaction technique. A single-phase perovskite structure of the ceramics was identified by the x-ray diffraction technique. The basic phase transition temperatures in these compositions were studied in the temperature range of 70–575 K. The tetragonal to cubic transition temperature was found to decrease with increasing Zr content. The orthorhombic to tetragonal transition temperature that increases with an initial increase in Zr content merges with the tetragonal–cubic transition for x⩾0.15 compositions. Raman spectra of rhombohedral and orthorhombic phases could not be distinguished. Excellent agreement between the crystallographic transition temperatures obtained by both techniques suggested that Zr substituted octahedra were uniformly distributed in the material without introducing any mechanical stress.

Bibliography

Dobal, P. S., Dixit, A., Katiyar, R. S., Yu, Z., Guo, R., & Bhalla, A. S. (2001). Micro-Raman scattering and dielectric investigations of phase transition behavior in the BaTiO3âBaZrO3 system. Journal of Applied Physics, 89(12), 8085â8091.

Authors 6

P. S. Dobal (first)
A. Dixit (additional)
R. S. Katiyar (additional)
Z. Yu (additional)
R. Guo (additional)
A. S. Bhalla (additional)

References 38 Referenced 327

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 10:17 a.m.)
Deposited	1 year, 6 months ago (Feb. 6, 2024, 8:22 p.m.)
Indexed	1 month, 1 week ago (July 25, 2025, 6:42 a.m.)
Issued	24 years, 2 months ago (June 15, 2001)
Published	24 years, 2 months ago (June 15, 2001)
Published Print	24 years, 2 months ago (June 15, 2001)

Funders 0

None

BibTeX

@article{Dobal_2001, title={Micro-Raman scattering and dielectric investigations of phase transition behavior in the BaTiO3–BaZrO3 system}, volume={89}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1369399}, DOI={10.1063/1.1369399}, number={12}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Dobal, P. S. and Dixit, A. and Katiyar, R. S. and Yu, Z. and Guo, R. and Bhalla, A. S.}, year={2001}, month=jun, pages={8085–8091} }

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