DOI: 10.1063/1.1365412. Anatase TiO2 thin films grown on lattice-matched LaAlO3 substrate by laser molecular-beam epitaxy

Anatase TiO2 thin films grown on lattice-matched LaAlO3 substrate by laser molecular-beam epitaxy

10.1063/1.1365412

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

Epitaxial anatase thin films were fabricated on lattice-matched (−0.2%) LaAlO3 (001) substrates in the layer-by-layer fashion by laser molecular-beam epitaxy. X-ray diffraction and transmission electron microscope show the films to exhibit high crystallinity and atomically defined interfaces. By virtue of the adoption of LaAlO3 substrate, which is transparent to photoexcitation of TiO2, optical band gaps could be determined to be 3.3 eV at room temperature. A photoluminescence band due to recombination of self-trapped excitons was observed at 5 K to give the peak maximum at 2.2 eV. As a result of the high degree of orientation of the epitaxial films, anisotropic optical absorption was clearly observed.

Bibliography

Murakami, M., Matsumoto, Y., Nakajima, K., Makino, T., Segawa, Y., Chikyow, T., Ahmet, P., Kawasaki, M., & Koinuma, H. (2001). Anatase TiO2 thin films grown on lattice-matched LaAlO3 substrate by laser molecular-beam epitaxy. Applied Physics Letters, 78(18), 2664â2666.

Authors 9

M. Murakami (first)
Y. Matsumoto (additional)
K. Nakajima (additional)
T. Makino (additional)
Y. Segawa (additional)
T. Chikyow (additional)
P. Ahmet (additional)
M. Kawasaki (additional)
H. Koinuma (additional)

References 12 Referenced 143

{'key': '2024020320002741800_r1', 'first-page': '469', 'volume': '31', 'year': '1989', 'journal-title': 'Shokubai (catalyst)'} / Shokubai (catalyst) (1989)
10.1016/S0022-0248(96)00423-X / J. Cryst. Growth (1996)
10.1063/1.356306 / J. Appl. Phys. (1994)
10.1016/0022-0248(93)90842-K / J. Cryst. Growth (1993)
10.1016/0038-1098(94)90889-3 / Solid State Commun. (1994)
10.1116/1.578587 / J. Vac. Sci. Technol. A (1993)
10.1143/JJAP.36.7358 / Jpn. J. Appl. Phys., Part 1 (1997)
10.1117/12.385421 / Proc. SPIE (2000)
10.1143/JJAP.38.L603 / Jpn. J. Appl. Phys., Part 2 (1999)
10.1016/S0167-5729(00)00005-4 / Surf. Sci. Rep. (2000)
10.1016/0038-1098(93)90427-O / Solid State Commun. (1993)
10.1103/PhysRevB.61.7459 / Phys. Rev. B (2000)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 10:16 a.m.)
Deposited	1 year, 6 months ago (Feb. 3, 2024, 3 p.m.)
Indexed	1 month, 3 weeks ago (July 2, 2025, 2:11 p.m.)
Issued	24 years, 3 months ago (April 30, 2001)
Published	24 years, 3 months ago (April 30, 2001)
Published Print	24 years, 3 months ago (April 30, 2001)

Funders 0

None

BibTeX

@article{Murakami_2001, title={Anatase TiO2 thin films grown on lattice-matched LaAlO3 substrate by laser molecular-beam epitaxy}, volume={78}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.1365412}, DOI={10.1063/1.1365412}, number={18}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Murakami, M. and Matsumoto, Y. and Nakajima, K. and Makino, T. and Segawa, Y. and Chikyow, T. and Ahmet, P. and Kawasaki, M. and Koinuma, H.}, year={2001}, month=apr, pages={2664–2666} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        2
      ]
    ],
    "date-time": "2025-07-02T18:11:19Z",
    "timestamp": 1751479879866
  },
  "reference-count": 12,
  "publisher": "AIP Publishing",
  "issue": "18",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        2001,
        4,
        30
      ]
    ]
  },
  "abstract": "<jats:p>Epitaxial anatase thin films were fabricated on lattice-matched (\u22120.2%)\u2008LaAlO3 (001) substrates in the layer-by-layer fashion by laser molecular-beam epitaxy. X-ray diffraction and transmission electron microscope show the films to exhibit high crystallinity and atomically defined interfaces. By virtue of the adoption of LaAlO3 substrate, which is transparent to photoexcitation of TiO2, optical band gaps could be determined to be 3.3 eV at room temperature. A photoluminescence band due to recombination of self-trapped excitons was observed at 5 K to give the peak maximum at 2.2 eV. As a result of the high degree of orientation of the epitaxial films, anisotropic optical absorption was clearly observed.</jats:p>",
  "DOI": "10.1063/1.1365412",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2002,
        7,
        26
      ]
    ],
    "date-time": "2002-07-26T14:16:02Z",
    "timestamp": 1027692962000
  },
  "page": "2664-2666",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 143,
  "title": "Anatase TiO2 thin films grown on lattice-matched LaAlO3 substrate by laser molecular-beam epitaxy",
  "prefix": "10.1063",
  "volume": "78",
  "author": [
    {
      "given": "M.",
      "family": "Murakami",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku Yokohama\u2009226-8503, Japan"
        }
      ]
    },
    {
      "given": "Y.",
      "family": "Matsumoto",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku Yokohama\u2009226-8503, Japan"
        }
      ]
    },
    {
      "given": "K.",
      "family": "Nakajima",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku Yokohama\u2009226-8503, Japan"
        }
      ]
    },
    {
      "given": "T.",
      "family": "Makino",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Photodynamics Research Center, RIKEN (Institute of Physical and Chemical Research), Sendai\u2009980-0845, Japan"
        }
      ]
    },
    {
      "given": "Y.",
      "family": "Segawa",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Photodynamics Research Center, RIKEN (Institute of Physical and Chemical Research), Sendai\u2009980-0845, Japan"
        }
      ]
    },
    {
      "given": "T.",
      "family": "Chikyow",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "National Institute for Research in Inorganic Materials, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan and National Research Institute for Metals, 1-2-1 Sngen, Ibaraki 305-0047, Japan"
        }
      ]
    },
    {
      "given": "P.",
      "family": "Ahmet",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "National Institute for Research in Inorganic Materials, 1-1 Namiki, Tsukuba, Ibaraki\u2009305-0044, Japan"
        }
      ]
    },
    {
      "given": "M.",
      "family": "Kawasaki",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Innovative and Engineered Materials, Tokyo Institute of Technology, 4259 Nagatsuta Midori-ku, Yokohama\u2009226-8502, Japan"
        }
      ]
    },
    {
      "given": "H.",
      "family": "Koinuma",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Frontier Collaborative Research Center, Tokyo Institute of Technology, Yokohama\u2009226-8503, Japan"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020320002741800_r1",
      "first-page": "469",
      "volume": "31",
      "year": "1989",
      "journal-title": "Shokubai (catalyst)"
    },
    {
      "key": "2024020320002741800_r2",
      "doi-asserted-by": "crossref",
      "first-page": "496",
      "DOI": "10.1016/S0022-0248(96)00423-X",
      "volume": "169",
      "year": "1996",
      "journal-title": "J. Cryst. Growth"
    },
    {
      "key": "2024020320002741800_r3",
      "doi-asserted-by": "crossref",
      "first-page": "2042",
      "DOI": "10.1063/1.356306",
      "volume": "75",
      "year": "1994",
      "journal-title": "J. Appl. Phys."
    },
    {
      "key": "2024020320002741800_r4",
      "doi-asserted-by": "crossref",
      "first-page": "108",
      "DOI": "10.1016/0022-0248(93)90842-K",
      "volume": "130",
      "year": "1993",
      "journal-title": "J. Cryst. Growth"
    },
    {
      "key": "2024020320002741800_r5",
      "doi-asserted-by": "crossref",
      "first-page": "267",
      "DOI": "10.1016/0038-1098(94)90889-3",
      "volume": "92",
      "year": "1994",
      "journal-title": "Solid State Commun."
    },
    {
      "key": "2024020320002741800_r6",
      "doi-asserted-by": "crossref",
      "first-page": "2419",
      "DOI": "10.1116/1.578587",
      "volume": "11",
      "year": "1993",
      "journal-title": "J. Vac. Sci. Technol. A"
    },
    {
      "key": "2024020320002741800_r7",
      "doi-asserted-by": "crossref",
      "first-page": "7358",
      "DOI": "10.1143/JJAP.36.7358",
      "volume": "36",
      "year": "1997",
      "journal-title": "Jpn. J. Appl. Phys., Part 1"
    },
    {
      "key": "2024020320002741800_r8",
      "doi-asserted-by": "crossref",
      "first-page": "19",
      "DOI": "10.1117/12.385421",
      "volume": "3941",
      "year": "2000",
      "journal-title": "Proc. SPIE"
    },
    {
      "key": "2024020320002741800_r9",
      "doi-asserted-by": "crossref",
      "first-page": "L603",
      "DOI": "10.1143/JJAP.38.L603",
      "volume": "38",
      "year": "1999",
      "journal-title": "Jpn. J. Appl. Phys., Part 2"
    },
    {
      "key": "2024020320002741800_r10",
      "doi-asserted-by": "crossref",
      "first-page": "105",
      "DOI": "10.1016/S0167-5729(00)00005-4",
      "volume": "39",
      "year": "2000",
      "journal-title": "Surf. Sci. Rep."
    },
    {
      "key": "2024020320002741800_r11",
      "doi-asserted-by": "crossref",
      "first-page": "847",
      "DOI": "10.1016/0038-1098(93)90427-O",
      "volume": "87",
      "year": "1993",
      "journal-title": "Solid State Commun."
    },
    {
      "key": "2024020320002741800_r12",
      "doi-asserted-by": "crossref",
      "first-page": "7459",
      "DOI": "10.1103/PhysRevB.61.7459",
      "volume": "61",
      "year": "2000",
      "journal-title": "Phys. Rev. B"
    }
  ],
  "container-title": "Applied Physics Letters",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/apl/article-pdf/78/18/2664/18557284/2664_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/apl/article-pdf/78/18/2664/18557284/2664_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        3
      ]
    ],
    "date-time": "2024-02-03T20:00:37Z",
    "timestamp": 1706990437000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/apl/article/78/18/2664/517139/Anatase-TiO2-thin-films-grown-on-lattice-matched"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2001,
        4,
        30
      ]
    ]
  },
  "references-count": 12,
  "journal-issue": {
    "issue": "18",
    "published-print": {
      "date-parts": [
        [
          2001,
          4,
          30
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1365412",
  "relation": {},
  "ISSN": [
    "0003-6951",
    "1077-3118"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        2001,
        4,
        30
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        2001,
        4,
        30
      ]
    ]
  }
}