DOI: 10.1063/1.1347001. Spin canting and size effects in nanoparticles of nonstoichiometric cobalt ferrite

Spin canting and size effects in nanoparticles of nonstoichiometric cobalt ferrite

10.1063/1.1347001

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

The magnetic properties of nonstoichiometric cobalt ferrite nanocrystals differing by their sizes were investigated by magnetic measurements and Fe57 Mössbauer spectroscopy. We found that the spin-wave Bloch exponent increases with increasing particle size, in agreement with previous studies. Under a magnetic field of 7 T, we observed that the partial reorientation of the two ferrimagnetic Fe3+ sublattice magnetizations towards the field direction increases with increasing the particle size; we discuss the applicability of an intrinsic spin canting model as a function of the particle size. An evaluation of the relative amounts of cobalt and iron in each spinel site is given.

Bibliography

Ngo, A. T., Bonville, P., & Pileni, M. P. (2001). Spin canting and size effects in nanoparticles of nonstoichiometric cobalt ferrite. Journal of Applied Physics, 89(6), 3370â3376.

Authors 3

A. T. Ngo (first)
P. Bonville (additional)
M. P. Pileni (additional)

References 33 Referenced 120

{'key': '2024020600154567800_r1', 'first-page': '120S', 'volume': '30S', 'year': '1959', 'journal-title': 'J. Appl. Phys.'} / J. Appl. Phys. (1959)
{'key': '2024020600154567800_r2', 'first-page': '643', 'volume': '235–238', 'year': '1997', 'journal-title': 'Mater. Sci. Forum'} / Mater. Sci. Forum (1997)
10.1103/PhysRevLett.79.4014 / Phys. Rev. Lett. (1997)
10.1103/PhysRevLett.80.181 / Phys. Rev. Lett. (1998)
10.1063/1.370357 / J. Appl. Phys. (1999)
{'key': '2024020600154567800_r6'}
{'key': '2024020600154567800_r7', 'first-page': '191', 'volume': '196', 'year': '1999', 'journal-title': 'J. Magn. Magn. Mater.'} / J. Magn. Magn. Mater. (1999)
{'key': '2024020600154567800_r7a', 'first-page': '191', 'volume': '197', 'year': '1999', 'journal-title': 'J. Magn. Magn. Mater.'} / J. Magn. Magn. Mater. (1999)
10.1016/0304-8853(87)90044-8 / J. Magn. Magn. Mater. (1987)
10.1021/jp970893q / J. Phys. Chem. B (1997)
10.1557/JMR.1997.0291 / J. Mater. Res. (1997)
10.1016/S0167-577X(96)00200-5 / Mater. Lett. (1997)
10.1016/0304-8853(95)00340-1 / J. Magn. Magn. Mater. (1995)
10.1021/jp9524136 / J. Phys. Chem. (1996)
{'key': '2024020600154567800_r14', 'first-page': '3927', 'volume': '13', 'year': '1996', 'journal-title': 'Langmuir'} / Langmuir (1996)
10.1007/s100510050801 / Eur. Phys. J. B (1999)
10.1063/1.1658812 / J. Appl. Phys. (1970)
{'key': '2024020600154567800_r17', 'first-page': '83', 'volume': '6', 'year': '1954', 'journal-title': 'Adv. Electron. Electron Phys.'} / Adv. Electron. Electron Phys. (1954)
{'key': '2024020600154567800_r18', 'first-page': '1393', 'volume': '86–88B', 'year': '1977', 'journal-title': 'Physica'} / Physica (1977)
{'key': '2024020600154567800_r19', 'first-page': '2779', 'volume': '5', 'year': '1993', 'journal-title': 'J. Phys.: Condens. Matter'} / J. Phys.: Condens. Matter (1993)
{'key': '2024020600154567800_r20', 'first-page': '559', 'volume': 'A240', 'year': '1948', 'journal-title': 'Philos. Trans. R. Soc. London, Ser. A'} / Philos. Trans. R. Soc. London, Ser. A (1948)
10.1109/TMAG.1991.1183750 / IEEE Trans. Magn. (1991)
{'key': '2024020600154567800_r21', 'first-page': '1577', 'volume': '104–107', 'year': '1992', 'journal-title': 'J. Magn. Magn. Mater.'} / J. Magn. Magn. Mater. (1992)
10.1016/0304-8853(93)90125-L / J. Magn. Magn. Mater. (1993)
10.1103/PhysRevB.54.9288 / Phys. Rev. B (1996)
10.1103/PhysRevB.58.14167 / Phys. Rev. B (1998)
10.1063/1.1656224 / J. Appl. Phys. (1968)
10.1007/BF02146310 / Hyperfine Interact. (1995)
10.1007/BF00895017 / Appl. Phys. (1976)
10.1021/jp953324w / J. Phys. Chem. (1996)
{'key': '2024020600154567800_r29'}
10.1051/rphysap:01981001606027500 / Rev. Phys. Appl. (1981)
10.1109/20.280834 / IEEE Trans. Magn. (1993)

Dates

Type	When
Created	23 years ago (July 26, 2002, 10:14 a.m.)
Deposited	1 year, 6 months ago (Feb. 5, 2024, 7:40 p.m.)
Indexed	1 month, 2 weeks ago (July 7, 2025, 9:06 a.m.)
Issued	24 years, 5 months ago (March 15, 2001)
Published	24 years, 5 months ago (March 15, 2001)
Published Print	24 years, 5 months ago (March 15, 2001)

Funders 0

None

BibTeX

@article{Ngo_2001, title={Spin canting and size effects in nanoparticles of nonstoichiometric cobalt ferrite}, volume={89}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1347001}, DOI={10.1063/1.1347001}, number={6}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Ngo, A. T. and Bonville, P. and Pileni, M. P.}, year={2001}, month=mar, pages={3370–3376} }

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