DOI: 10.1063/1.1345840. Excited-state quenching of a highly luminescent conjugated polymer

Excited-state quenching of a highly luminescent conjugated polymer

10.1063/1.1345840

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

The optical properties of a luminescent polymer, poly[1,4-phenylene-1,2-di(phenoxyphenyl) vinylene], have been investigated. Its photoluminescence yield increases unusually in the solid-state over solution, 52%–6% respectively. Investigations into the stimulated emission properties of this material were carried out but no amplified spontaneous emission was observed. To investigate the presence of excited-state absorption features, the photoinduced absorption spectrum was measured. An observed polaron absorption band, from 1.5 to 2.25 eV, overlaps the emission spectra and therefore quenches stimulated emission. This highlights the need to consider the effects of excited-state absorption on the emission when synthesizing new materials.

Bibliography

Belton, C., OâBrien, D. F., Blau, W. J., Cadby, A. J., Lane, P. A., Bradley, D. D. C., Byrne, H. J., Stockmann, R., & HÃ¶rhold, H.-H. (2001). Excited-state quenching of a highly luminescent conjugated polymer. Applied Physics Letters, 78(8), 1059â1061.

Authors 9

C. Belton (first)
D. F. O’Brien (additional)
W. J. Blau (additional)
A. J. Cadby (additional)
P. A. Lane (additional)
D. D. C. Bradley (additional)
H. J. Byrne (additional)
R. Stockmann (additional)
H-H. Hörhold (additional)

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10.1016/S0925-3467(97)00111-0 / Opt. Mater. (1998)
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{'key': '2024020319383789200_r15'}
10.1016/S0040-6090(96)09159-6 / Thin Solid Films (1997)
10.1016/0032-3861(82)90210-5 / Polymer (1982)
{'key': '2024020319383789200_r18'}
{'key': '2024020319383789200_r19'}
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 10:14 a.m.)
Deposited	1 year, 6 months ago (Feb. 3, 2024, 2:39 p.m.)
Indexed	1 year, 6 months ago (Feb. 3, 2024, 3:10 p.m.)
Issued	24 years, 6 months ago (Feb. 19, 2001)
Published	24 years, 6 months ago (Feb. 19, 2001)
Published Print	24 years, 6 months ago (Feb. 19, 2001)

Funders 0

None

BibTeX

@article{Belton_2001, title={Excited-state quenching of a highly luminescent conjugated polymer}, volume={78}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.1345840}, DOI={10.1063/1.1345840}, number={8}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Belton, C. and O’Brien, D. F. and Blau, W. J. and Cadby, A. J. and Lane, P. A. and Bradley, D. D. C. and Byrne, H. J. and Stockmann, R. and Hörhold, H-H.}, year={2001}, month=feb, pages={1059–1061} }

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