DOI: 10.1063/1.1323977. Depletion interaction between spheres immersed in a solution of ideal polymer chains

Depletion interaction between spheres immersed in a solution of ideal polymer chains

10.1063/1.1323977

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The depletion interaction between two spheres due to nonadsorbing ideal polymers is calculated from the polymer concentration profile using the excess (negative) adsorption. Computer simulations show that the polymer concentration profiles around two spheres are well described by the product function of the concentration profile around a single sphere. From the interaction potential between two spheres the second osmotic virial coefficient, B2, is calculated for various polymer-colloid size ratios. We find that when the polymers become smaller than the spheres, B2 remains positive in the dilute regime. This shows that the depletion interaction is ineffective for relatively small spheres.

Bibliography

Tuinier, R., Vliegenthart, G. A., & Lekkerkerker, H. N. W. (2000). Depletion interaction between spheres immersed in a solution of ideal polymer chains. The Journal of Chemical Physics, 113(23), 10768â10775.

Authors 3

Remco Tuinier (first)
Gerrit A. Vliegenthart (additional)
Henk N. W. Lekkerkerker (additional)

References 47 Referenced 119

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 10:14 a.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 4:39 p.m.)
Indexed	4 weeks, 2 days ago (Aug. 2, 2025, 1 a.m.)
Issued	24 years, 8 months ago (Dec. 15, 2000)
Published	24 years, 8 months ago (Dec. 15, 2000)
Published Print	24 years, 8 months ago (Dec. 15, 2000)

Funders 0

None

BibTeX

@article{Tuinier_2000, title={Depletion interaction between spheres immersed in a solution of ideal polymer chains}, volume={113}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1323977}, DOI={10.1063/1.1323977}, number={23}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Tuinier, Remco and Vliegenthart, Gerrit A. and Lekkerkerker, Henk N. W.}, year={2000}, month=dec, pages={10768–10775} }

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