DOI: 10.1063/1.1323548. Polarized photoluminescence from solid films of nematic and chiral-nematic poly(p-phenylene)s

Polarized photoluminescence from solid films of nematic and chiral-nematic poly(p-phenylene)s

10.1063/1.1323548

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

Thermotropic nematic and chiral-nematic poly(p-phenylene)s were prepared into well-aligned films between fused-silica substrates in which conjugated backbones were uniaxially and helically oriented. With unpolarized photoexcitation at 350 nm, a nematic film produced a degree of linear polarization of 9 near the emission peak at 410 nm with no evidence of excimer formation. With the same photoexcitation of a chiral-nematic film, the degree of circular polarization was found to vary from −1.3 in the 390–430 nm spectral region to between +0.3 and +0.9 beyond the edge of the selective reflection band. The crossover behavior unique to light emission from the selective reflection region remains inexplicable with existing theories on light propagation through periodically structured films.

Bibliography

Katsis, D., Chen, H. P., Chen, S. H., Rothberg, L. J., & Tsutsui, T. (2000). Polarized photoluminescence from solid films of nematic and chiral-nematic poly(p-phenylene)s. Applied Physics Letters, 77(19), 2982â2984.

Authors 5

D. Katsis (first)
H. P. Chen (additional)
S. H. Chen (additional)
L. J. Rothberg (additional)
T. Tsutsui (additional)

References 21 Referenced 9

{'key': '2024020319030888600_r1'}
10.1038/347539a0 / Nature (London) (1990)
10.1038/382695a0 / Nature (London) (1996)
10.1002/(SICI)1521-4095(199803)10:5<365::AID-ADMA365>3.0.CO;2-U / Adv. Mater. (1998)
{'key': '2024020319030888600_r5'}
10.1038/42190 / Nature (London) (1997)
10.1002/masy.19961040116 / Macromol. Symp. (1996)
10.1002/adma.19950071112 / Adv. Mater. (1995)
10.1002/adma.19960080209 / Adv. Mater. (1996)
10.1126/science.279.5352.835 / Science (1998)
10.1002/(SICI)1521-4095(199906)11:8<671::AID-ADMA671>3.0.CO;2-E / Adv. Mater. (1999)
10.1021/ma980945p / Macromolecules (1998)
10.1021/cm000238m / Chem. Mater. (2000)
10.1080/026782999205317 / Liq. Cryst. (1999)
10.1038/17343 / Nature (London) (1999)
10.1364/JOSAA.11.002145 / J. Opt. Soc. Am. A (1994)
10.1021/ja9600643 / J. Am. Chem. Soc. (1996)
10.1021/ja971912c / J. Am. Chem. Soc. (1997)
10.1002/(SICI)1521-4095(200004)12:8<589::AID-ADMA589>3.0.CO;2-C / Adv. Mater. (2000)
10.1002/(SICI)1521-4095(200003)12:5<362::AID-ADMA362>3.0.CO;2-P / Adv. Mater. (2000)
10.1002/(SICI)1521-4095(199908)11:11<895::AID-ADMA895>3.0.CO;2-Y / Adv. Mater. (1999)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:41 a.m.)
Deposited	1 year, 6 months ago (Feb. 3, 2024, 2:03 p.m.)
Indexed	1 year, 6 months ago (Feb. 3, 2024, 2:40 p.m.)
Issued	24 years, 9 months ago (Nov. 6, 2000)
Published	24 years, 9 months ago (Nov. 6, 2000)
Published Print	24 years, 9 months ago (Nov. 6, 2000)

Funders 0

None

BibTeX

@article{Katsis_2000, title={Polarized photoluminescence from solid films of nematic and chiral-nematic poly(p-phenylene)s}, volume={77}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.1323548}, DOI={10.1063/1.1323548}, number={19}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Katsis, D. and Chen, H. P. and Chen, S. H. and Rothberg, L. J. and Tsutsui, T.}, year={2000}, month=nov, pages={2982–2984} }

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