DOI: 10.1063/1.123833. Hydrogen adsorption and cohesive energy of single-walled carbon nanotubes

Hydrogen adsorption and cohesive energy of single-walled carbon nanotubes

10.1063/1.123833

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

Hydrogen adsorption on crystalline ropes of carbon single-walled nanotubes (SWNT) was found to exceed 8 wt. %, which is the highest capacity of any carbon material. Hydrogen is first adsorbed on the outer surfaces of the crystalline ropes. At pressures higher than about 40 bar at 80 K, however, a phase transition occurs where there is a separation of the individual SWNTs, and hydrogen is physisorbed on their exposed surfaces. The pressure of this phase transition provides a tube-tube cohesive energy for much of the material of 5 meV/C atom. This small cohesive energy is affected strongly by the quality of crystalline order in the ropes.

Bibliography

Ye, Y., Ahn, C. C., Witham, C., Fultz, B., Liu, J., Rinzler, A. G., Colbert, D., Smith, K. A., & Smalley, R. E. (1999). Hydrogen adsorption and cohesive energy of single-walled carbon nanotubes. Applied Physics Letters, 74(16), 2307â2309.

Authors 9

Y. Ye (first)
C. C. Ahn (additional)
C. Witham (additional)
B. Fultz (additional)
J. Liu (additional)
A. G. Rinzler (additional)
D. Colbert (additional)
K. A. Smith (additional)
R. E. Smalley (additional)

References 27 Referenced 763

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Dates

Type	When
Created	23 years ago (July 26, 2002, 8:42 a.m.)
Deposited	1 year, 6 months ago (Feb. 3, 2024, 11:05 a.m.)
Indexed	21 hours, 24 minutes ago (Aug. 21, 2025, 1:57 p.m.)
Issued	26 years, 4 months ago (April 19, 1999)
Published	26 years, 4 months ago (April 19, 1999)
Published Print	26 years, 4 months ago (April 19, 1999)

Funders 0

None

BibTeX

@article{Ye_1999, title={Hydrogen adsorption and cohesive energy of single-walled carbon nanotubes}, volume={74}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.123833}, DOI={10.1063/1.123833}, number={16}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Ye, Y. and Ahn, C. C. and Witham, C. and Fultz, B. and Liu, J. and Rinzler, A. G. and Colbert, D. and Smith, K. A. and Smalley, R. E.}, year={1999}, month=apr, pages={2307–2309} }

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