Abstract
High-quality single crystals of α-quaterthiophene (α-4T) and α-hexathiophene (α-6T) were investigated to compare intrinsic bulk and surface electrical properties. The bulk properties of these organic p-type semiconductors are derived from extended current–voltage characteristics and the surface properties from single crystal field-effect transistor measurements. Most significantly, charge carrier mobilities as high as 0.5 cm2/V s are observed in α-6T both in the bulk and at the surface. The high quality and purity of the crystals are evident from the low trap densities(<1015 cm−3) and the even lower dopant concentrations (2×1013 for α-4T and 7×1010 cm−3 for α-6T). These intrinsically high performance figures, together with the ease of processing, make these oligothiophenes attractive materials for “plastic electronic” devices.
References
12
Referenced
36
10.1016/0038-1098(89)90121-X
/ Solid State Commun. (1989)10.1063/1.105158
/ Appl. Phys. Lett. (1991)10.1063/1.103182
/ Appl. Phys. Lett. (1990)10.1126/science.268.5208.270
/ Science (1995)10.1109/55.556089
/ IEEE Electron Device Lett. (1997)10.1063/1.363032
/ J. Appl. Phys. (1996)10.1109/16.605476
/ IEEE Trans. Electron Devices (1997)10.1016/S0022-0248(97)00370-9
/ J. Cryst. Growth (1997){'key': '2024020315250391200_r9'}
10.1002/adma.19960080109
/ Adv. Mater. (1996){'key': '2024020315250391200_r11'}
{'key': '2024020315250391200_r12', 'first-page': '355', 'volume': '5', 'year': '1995', 'journal-title': 'J. Phys. III'}
/ J. Phys. III (1995)
Dates
Type | When |
---|---|
Created | 23 years, 1 month ago (July 26, 2002, 9:31 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 3, 2024, 10:25 a.m.) |
Indexed | 1 year, 5 months ago (April 2, 2024, 1:21 p.m.) |
Issued | 26 years, 8 months ago (Dec. 14, 1998) |
Published | 26 years, 8 months ago (Dec. 14, 1998) |
Published Print | 26 years, 8 months ago (Dec. 14, 1998) |
@article{Sch_n_1998, title={Surface and bulk mobilities of oligothiophene single crystals}, volume={73}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.122828}, DOI={10.1063/1.122828}, number={24}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Schön, J. H. and Kloc, Ch. and Laudise, R. A. and Batlogg, B.}, year={1998}, month=dec, pages={3574–3576} }