DOI: 10.1063/1.121373. Crystal orientation dependence of piezoelectric properties of lead zirconate titanate near the morphotropic phase boundary

Crystal orientation dependence of piezoelectric properties of lead zirconate titanate near the morphotropic phase boundary

10.1063/1.121373

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

The piezoelectric and dielectric constants in different crystal orientations of the lead zirconate titanate (PZT) have been phenomenologically calculated for the compositions near the morphotropic phase boundary at room temperature. For a tetragonal PZT, the effective piezoelectric constant d33 monotonously decreases as the crystal cutting angle from the spontaneous polarization direction [001] increases. However, for a rhombohedral PZT, the effective piezoelectric constant d33[001]// along the perovskite [001] direction was found to be much larger than those along the spontaneous polarization direction [111]. This crystal orientation-related enhancement is emphasized as the composition approaches the morphotropic phase boundary. This suggests that by adopting the perovskite [001] orientation with a rhombohedral composition near the morphotropic phase boundary, the piezoelectric constant d33 for PZT can be greatly enhanced.

Bibliography

Du, X., Zheng, J., Belegundu, U., & Uchino, K. (1998). Crystal orientation dependence of piezoelectric properties of lead zirconate titanate near the morphotropic phase boundary. Applied Physics Letters, 72(19), 2421â2423.

Authors 4

Xiao-hong Du (first)
Jiehui Zheng (additional)
Uma Belegundu (additional)
Kenji Uchino (additional)

References 11 Referenced 389

10.1557/S0883769400035934 / MRS Bull. (1996)
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10.1016/0924-4247(96)01139-9 / Sens. Actuators A (1996)
10.1143/JJAP.33.5328 / Jpn. J. Appl. Phys., Part 1 (1994)
10.1063/1.344419 / J. Appl. Phys. (1989)
10.1143/JJAP.33.5155 / Jpn. J. Appl. Phys., Part 1 (1994)
10.1063/1.358467 / J. Appl. Phys. (1994)
10.1143/JJAP.36.5580 / Jpn. J. Appl. Phys., Part 1 (1997)
10.1080/00150198908221436 / Ferroelectrics (1989)
10.1109/JRPROC.1960.287467 / Proc. IRE (1960)
10.1143/JJAP.6.1079 / Jpn. J. Appl. Phys. (1967)

Dates

Type	When
Created	23 years ago (July 26, 2002, 9:43 a.m.)
Deposited	1 year, 6 months ago (Feb. 3, 2024, 9:19 a.m.)
Indexed	2 days, 5 hours ago (Aug. 19, 2025, 6:38 a.m.)
Issued	27 years, 3 months ago (May 11, 1998)
Published	27 years, 3 months ago (May 11, 1998)
Published Print	27 years, 3 months ago (May 11, 1998)

Funders 0

None

BibTeX

@article{Du_1998, title={Crystal orientation dependence of piezoelectric properties of lead zirconate titanate near the morphotropic phase boundary}, volume={72}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.121373}, DOI={10.1063/1.121373}, number={19}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Du, Xiao-hong and Zheng, Jiehui and Belegundu, Uma and Uchino, Kenji}, year={1998}, month=may, pages={2421–2423} }

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