DOI: 10.1063/1.117369. Synchrotron x-ray diffraction studies of the structural properties of electrode materials in operating battery cells

Synchrotron x-ray diffraction studies of the structural properties of electrode materials in operating battery cells

10.1063/1.117369

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

Hard x rays from a synchrotron source were utilized in diffraction experiments which probed the bulk of electrode materials while they were operating in situ in battery cells. Two technologically relevant electrode materials were examined; an AB2-type anode in a nickel–metal–hydride cell and a LiMn2O4 cathode in a Li-ion ‘‘rocking chair’’ cell. Structural features such as lattice expansions and contractions, phase transitions, and the formation of multiple phases were easily observed as either hydrogen or lithium was electrochemically intercalated in and out of the electrode materials. The relevance of this technique for future studies of battery electrode materials is discussed.

Bibliography

Thurston, T. R., Jisrawi, N. M., Mukerjee, S., Yang, X. Q., McBreen, J., Daroux, M. L., & Xing, X. K. (1996). Synchrotron x-ray diffraction studies of the structural properties of electrode materials in operating battery cells. Applied Physics Letters, 69(2), 194â196.

Authors 7

T. R. Thurston (first)
N. M. Jisrawi (additional)
S. Mukerjee (additional)
X. Q. Yang (additional)
J. McBreen (additional)
M. L. Daroux (additional)
X. K. Xing (additional)

References 6 Referenced 32

{'key': '2024020311070207800_r1'}
{'key': '2024020311070207800_r2', 'first-page': '59', 'article-title': 'J. Alloys Compd.', 'volume': '189', 'year': '1992'} / J. Alloys Compd. (1992)
{'key': '2024020311070207800_r3', 'first-page': '304', 'article-title': 'Nucl. Instrum. Methods A', 'volume': '336', 'year': '1993'} / Nucl. Instrum. Methods A (1993)
{'key': '2024020311070207800_r4', 'first-page': '2278', 'article-title': 'J. Electrochem. Soc.', 'volume': '142', 'year': '1995'} / J. Electrochem. Soc. (1995)
{'key': '2024020311070207800_r5'}
{'key': '2024020311070207800_r6', 'first-page': '101', 'article-title': 'J. Alloys Compd.', 'volume': '218', 'year': '1995'} / J. Alloys Compd. (1995)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:40 a.m.)
Deposited	1 year, 7 months ago (Feb. 3, 2024, 6:07 a.m.)
Indexed	1 year, 6 months ago (Feb. 14, 2024, 4:01 a.m.)
Issued	29 years, 1 month ago (July 8, 1996)
Published	29 years, 1 month ago (July 8, 1996)
Published Print	29 years, 1 month ago (July 8, 1996)

Funders 0

None

BibTeX

@article{Thurston_1996, title={Synchrotron x-ray diffraction studies of the structural properties of electrode materials in operating battery cells}, volume={69}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.117369}, DOI={10.1063/1.117369}, number={2}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Thurston, T. R. and Jisrawi, N. M. and Mukerjee, S. and Yang, X. Q. and McBreen, J. and Daroux, M. L. and Xing, X. K.}, year={1996}, month=jul, pages={194–196} }

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