DOI: 10.1063/1.116362. <i>In</i> <i>situ</i> x-ray diffraction study of the antiferroelectric

In situ x-ray diffraction study of the antiferroelectric–ferroelectric phase transition in PLSnZT

10.1063/1.116362

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

In situ x-ray diffraction studies were performed on the PLSnZT antiferroelectric–ferroelectric phase switching ceramic and polycrystalline powder. The crystallography of both the antiferroelectic and electric-field-induced ferroelectric phases were determined for the approximate composition of Pb0.98La0.02(Zr0.55Sn0.33Ti0.12)0.995O3. A preferred antiferroelectric domain structure has been identified and possible mechanisms responsible for the domain structure are presented. A single tetragonal phase has been identified for the room temperature zero-field antiferroelectric material with unit cell dimensions a=4.107 Å and c=4.081 Å. An electric field-induced structure developing at the antiferroelectric–ferroelectric switching field has also been observed and determined to be of rhombohedral symmetry with a=4.105 Å and θ=89.85° indicating a volume increase of 0.49% for the tetragonal–rhombohedral transition.

Bibliography

Blue, C. T., Hicks, J. C., Park, S.-E., Yoshikawa, S., & Cross, L. E. (1996). Inâsitu x-ray diffraction study of the antiferroelectricâferroelectric phase transition in PLSnZT. Applied Physics Letters, 68(21), 2942â2944.

Authors 5

C. T. Blue (first)
J. C. Hicks (additional)
S.-E. Park (additional)
S. Yoshikawa (additional)
L. E. Cross (additional)

References 7 Referenced 53

{'key': '2024020310485080400_r1', 'first-page': '571', 'article-title': 'J. Am. Ceram. Soc.', 'volume': '72', 'year': '1989'} / J. Am. Ceram. Soc. (1989)
{'key': '2024020310485080400_r2', 'first-page': '6014', 'article-title': 'J. Appl. Phys.', 'volume': '66', 'year': '1989'} / J. Appl. Phys. (1989)
{'key': '2024020310485080400_r3', 'first-page': '195', 'article-title': 'Ferroelectrics', 'volume': '99', 'year': '1989'} / Ferroelectrics (1989)
{'key': '2024020310485080400_r4'}
{'key': '2024020310485080400_r5'}
{'key': '2024020310485080400_r6'}
{'key': '2024020310485080400_r7', 'first-page': '4301', 'article-title': 'J. Appl. Phys.', 'volume': '76', 'year': '1994'} / J. Appl. Phys. (1994)

Dates

Type	When
Created	23 years ago (July 26, 2002, 9:40 a.m.)
Deposited	1 year, 6 months ago (Feb. 3, 2024, 5:48 a.m.)
Indexed	2 months ago (June 17, 2025, 6:07 a.m.)
Issued	29 years, 3 months ago (May 20, 1996)
Published	29 years, 3 months ago (May 20, 1996)
Published Print	29 years, 3 months ago (May 20, 1996)

Funders 0

None

BibTeX

@article{Blue_1996, title={In situ x-ray diffraction study of the antiferroelectric–ferroelectric phase transition in PLSnZT}, volume={68}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.116362}, DOI={10.1063/1.116362}, number={21}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Blue, C. T. and Hicks, J. C. and Park, S.-E. and Yoshikawa, S. and Cross, L. E.}, year={1996}, month=may, pages={2942–2944} }

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