Abstract
The specific volumes of molten Pd40Ni40P20, Pd77Cu6.5Si16.5, Pd82Si18, and Ni80P20, which are all glass formers, and were measured near the liquidus. It was found that the ratio α/Tg, where α is the thermal expansion coefficient and Tg is the glass transition temperature, remains fairly constant for all these systems. The scaling follows from the fact that with a larger thermal expansion coefficient, the free volume of the molten system would be squeezed out faster resulting in a larger Tg. This scaling behavior also allows us to roughly predict the glass transition temperature of a glass forming system. The glass forming ability can also be predicted by a parameter defined as α/T1.
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@article{Chua_1995, title={Correlations for the thermal expansion coefficients of molten glass forming systems}, volume={67}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.115406}, DOI={10.1063/1.115406}, number={5}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Chua, L. F. and Yuen, C. W. and Kui, H. W.}, year={1995}, month=jul, pages={614–616} }