Abstract
We describe a fast temperature-jump (T-jump) apparatus capable of acquiring kinetic relaxation transients via real-time fluorescence detection over a time interval from nanoseconds to milliseconds in a single sweep. The method is suitable for aqueous solutions, relying upon the direct absorption of laser light by the bulk water. This obviates the need for additives (serving as optical or conductive heaters) that may interact with the sample under investigation. The longitudinal temperature profile is made uniform by counterpropagating heating pulses. Dead time is limited to one period of the probe laser (16 ns). The apparatus response is tested with aqueous tryptophan and the diffusion-controlled dimerization of proflavine.
References
21
Referenced
72
{'key': '2024021023414291500_r1'}
{'key': '2024021023414291500_r2'}
{'key': '2024021023414291500_r3'}
10.1063/1.1684958
/ Rev. Sci. Instrum. (1971){'key': '2024021023414291500_r5', 'first-page': '8378', 'volume': '86', 'year': '1989', 'journal-title': 'Proc. Natl. Acad. Sci. U.S.A.'}
/ Proc. Natl. Acad. Sci. U.S.A. (1989)10.1021/ja00760a020
/ J. Am. Chem. Soc. (1972){'key': '2024021023414291500_r7', 'first-page': '215', 'volume': '239', 'year': '1972', 'journal-title': 'Nature (London)'}
/ Nature (London) (1972){'key': '2024021023414291500_r8'}
{'key': '2024021023414291500_r9', 'first-page': '24', 'volume': '12', 'year': '1980', 'journal-title': 'Electro-opt. Sys. Des.'}
/ Electro-opt. Sys. Des. (1980){'key': '2024021023414291500_r10'}
10.1109/3.362703
/ IEEE J. Quantum Electron. (1994)10.1021/bi00436a025
/ Biochemistry (1989){'key': '2024021023414291500_r13'}
{'key': '2024021023414291500_r13a'}
{'key': '2024021023414291500_r14'}
10.1364/JOSA.64.001107
/ J. Opt. Soc. Am. (1974)10.1073/pnas.93.12.5759
/ Proc. Natl. Acad. Sci. U.S.A. (1996){'key': '2024021023414291500_r17'}
10.1021/j150664a037
/ J. Phys. Chem. (1984){'key': '2024021023414291500_r19'}
10.1039/tf9646000386
/ Trans. Faraday Soc. (1964)
Dates
Type | When |
---|---|
Created | 23 years, 1 month ago (July 26, 2002, 8:34 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 10, 2024, 6:41 p.m.) |
Indexed | 1 year ago (Aug. 12, 2024, 8:35 a.m.) |
Issued | 28 years, 10 months ago (Oct. 1, 1996) |
Published | 28 years, 10 months ago (Oct. 1, 1996) |
Published Print | 28 years, 10 months ago (Oct. 1, 1996) |
@article{Ballew_1996, title={A single-sweep, nanosecond time resolution laser temperature-jump apparatus}, volume={67}, ISSN={1089-7623}, url={http://dx.doi.org/10.1063/1.1147137}, DOI={10.1063/1.1147137}, number={10}, journal={Review of Scientific Instruments}, publisher={AIP Publishing}, author={Ballew, R. M. and Sabelko, J. and Reiner, C. and Gruebele, M.}, year={1996}, month=oct, pages={3694–3699} }