Abstract
The design of a high resolution ‘‘magnetic-bottle’’-type time-of-flight electron spectrometer suitable for the study of mass-separated metal and semiconductor cluster anions is described. A high collection efficiency is achieved by using magnetic fields to guide the photoelectrons, so that vibrationally resolved photoelectron spectra can be recorded at a low laser pulse energy (<10 μJ focused to 1 mm2) avoiding multiphoton processes. Spectra of clusters with a very low relative abundance, for example the products of chemical reactions involving clusters, can be recorded and an energy resolution of 6 meV (48 cm−1) achieved.
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Dates
Type | When |
---|---|
Created | 23 years, 1 month ago (July 26, 2002, 8:03 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 10, 2024, 10:38 a.m.) |
Indexed | 4 months, 4 weeks ago (April 9, 2025, 5:09 a.m.) |
Issued | 30 years, 2 months ago (July 1, 1995) |
Published | 30 years, 2 months ago (July 1, 1995) |
Published Print | 30 years, 2 months ago (July 1, 1995) |
@article{Handschuh_1995, title={Vibrational spectroscopy of clusters using a ‘“magnetic bottle”’ electron spectrometer}, volume={66}, ISSN={1089-7623}, url={http://dx.doi.org/10.1063/1.1145446}, DOI={10.1063/1.1145446}, number={7}, journal={Review of Scientific Instruments}, publisher={AIP Publishing}, author={Handschuh, H. and Ganteför, G. and Eberhardt, W.}, year={1995}, month=jul, pages={3838–3843} }