Abstract
We have investigated the interface formation of Ca with an alkanethiol CH3(CH3)17SH monolayer self-assembled onto gold-coated silicon. Deposited Ca neither diffused into nor interacted chemically with the monolayer. Core-level shift and work function changes were observed in the monolayer as soon as Ca was deposited and they were stabilized after 8 Å of Ca coverage. The shifts are interpreted in terms of charge transfer from Ca to the monolayer, creating a dipole layer at the interface.
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Dates
Type | When |
---|---|
Created | 23 years, 1 month ago (July 26, 2002, 9:07 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 3, 2024, 4:49 a.m.) |
Indexed | 1 year, 6 months ago (Feb. 3, 2024, 1:25 p.m.) |
Issued | 29 years, 9 months ago (Oct. 30, 1995) |
Published | 29 years, 9 months ago (Oct. 30, 1995) |
Published Print | 29 years, 9 months ago (Oct. 30, 1995) |
@article{Razafitrimo_1995, title={X-ray photoemission study of the interface formation between calcium and self-assembled alkanethiol monolayers}, volume={67}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.114315}, DOI={10.1063/1.114315}, number={18}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Razafitrimo, H. and Ettedgui, E. and Guo, L.-H. and McLendon, G. L. and Gao, Y.}, year={1995}, month=oct, pages={2621–2623} }