Abstract
We report the results of a vacuum ultraviolet (VUV) study of single crystal and polycrystalline AlN over the range 4–40 eV and compare these with theoretical optical properties calculated from first principles using an orthogonalized linear combination of atomic orbitals in the local density approximation. The electronic structure of AlN has a two-dimensional (2D) character indicated by logarithmic divergences at 8.7 and 14 eV. These mark the centers of two sets of 2D critical points which are associated with N 2p→Al 3s transitions and Al=N→Al 3p transitions, respectively. A third feature is centered at 33 eV and associated with N 2s→Al 3d transitions.
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Dates
Type | When |
---|---|
Created | 23 years, 1 month ago (July 26, 2002, 9:38 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 3, 2024, 1:08 a.m.) |
Indexed | 3 months ago (May 21, 2025, 12:48 p.m.) |
Issued | 31 years, 11 months ago (Aug. 30, 1993) |
Published | 31 years, 11 months ago (Aug. 30, 1993) |
Published Print | 31 years, 11 months ago (Aug. 30, 1993) |
@article{Loughin_1993, title={Electronic structure of aluminum nitride: Theory and experiment}, volume={63}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.109764}, DOI={10.1063/1.109764}, number={9}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Loughin, S. and French, R. H. and Ching, W. Y. and Xu, Y. N. and Slack, G. A.}, year={1993}, month=aug, pages={1182–1184} }