DOI: 10.1063/1.104920. Anomaly in C p/C v: A possible signature of a liquid-glass transition

Anomaly in C p/C v: A possible signature of a liquid-glass transition

10.1063/1.104920

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

Brillouin scattering from two classic glass-forming materials, ZnCl2 and glycerol, reveals a maximum in the ratio (γ) of specific heats Cp and Cv as a function of temperature. We propose that the temperature at which the maximum in γ occurs in our materials may be indicative of a ‘‘liquid-like’’ to ‘‘solid-like’’ transformation. As such it may be a convenient thermodynamic signature of a ‘glass’ transition.

Bibliography

Grimsditch, M., & Rivier, N. (1991). Anomaly in C p/C v: A possible signature of a liquid-glass transition. Applied Physics Letters, 58(21), 2345â2347.

Authors 2

M. Grimsditch (first)
N. Rivier (additional)

References 30 Referenced 16

{'key': '2024020302231766500_r1'}
10.1016/0022-3697(88)90002-9 / J. Chem. Solids (1988)
{'key': '2024020302231766500_r3'}
{'key': '2024020302231766500_r4'}
{'key': '2024020302231766500_r5'}
10.1063/1.443445 / J. Chem. Phys. (1982)
10.1139/p82-229 / Can. J. Phys. (1982)
10.1063/1.444896 / J. Chem. Phys. (1983)
10.1139/p83-163 / Can. J. Phys. (1983)
10.1063/1.446552 / J. Chem. Phys. (1984)
10.1016/0022-3093(88)90137-8 / J. Non. Cryst. Solids (1988)
{'key': '2024020302231766500_r12', 'first-page': '571', 'volume': '6', 'year': '1985', 'journal-title': 'Mater. Sci. Forum'} / Mater. Sci. Forum (1985)
10.1063/1.452031 / J. Chem. Phys. (1987)
10.1063/1.1727126 / J. Chem. Phys. (1966)
{'key': '2024020302231766500_r15'}
{'key': '2024020302231766500_r16'}
{'key': '2024020302231766500_r17'}
{'key': '2024020302231766500_r17a'}
{'key': '2024020302231766500_r18'}
10.1063/1.443817 / J. Chem. Phys. (1982)
10.1121/1.1909121 / J. Acoust. Soc. Am. (1957)
{'key': '2024020302231766500_r21'}
{'key': '2024020302231766500_r22', 'first-page': '363', 'volume': '19', 'year': '1987', 'journal-title': 'Physica Scripta T'} / Physica Scripta T (1987)
{'key': '2024020302231766500_r23'}
10.1103/PhysRevB.34.1835 / Phys. Rev. B (1986)
10.1103/PhysRevB.40.461 / Phys. Rev. B (1989)
10.1063/1.457331 / J. Chem. Phys. (1989)
10.1103/PhysRevA.29.2765 / Phys. Rev. A (1984)
10.1088/0022-3719/17/33/005 / J. Phys. C (1984)
10.1088/0022-3719/19/27/001 / J. Phys. C (1986)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:31 a.m.)
Deposited	1 year, 6 months ago (Feb. 2, 2024, 9:23 p.m.)
Indexed	1 year, 6 months ago (Feb. 7, 2024, 11:22 a.m.)
Issued	34 years, 3 months ago (May 27, 1991)
Published	34 years, 3 months ago (May 27, 1991)
Published Print	34 years, 3 months ago (May 27, 1991)

Funders 0

None

BibTeX

@article{Grimsditch_1991, title={Anomaly in C p/C v: A possible signature of a liquid-glass transition}, volume={58}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.104920}, DOI={10.1063/1.104920}, number={21}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Grimsditch, M. and Rivier, N.}, year={1991}, month=may, pages={2345–2347} }

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