DOI: 10.1039/c6cy00942e. Electrochemical behaviour of naked sub-nanometre sized copper clusters and effect of CO<sub>2</sub>

Electrochemical behaviour of naked sub-nanometre sized copper clusters and effect of CO2

10.1039/c6cy00942e

Crossref journal-article

Royal Society of Chemistry (RSC)

Catalysis Science & Technology (292)

Abstract

In size-controlled naked Cu5and Cu20nanoclusters the latter show anodic redox processes occurring at much lower potential with respect to Cu5, but the latter coordinate effectively CO2and allow to reduce CO2under cathodic conditions at lower overpotential.

Bibliography

Passalacqua, R., Parathoner, S., Centi, G., Halder, A., Tyo, E. C., Yang, B., Seifert, S., & Vajda, S. (2016). Electrochemical behaviour of naked sub-nanometre sized copper clusters and effect of CO2. Catalysis Science & Technology, 6(18), 6977â6985.

Authors 8

Rosalba Passalacqua (first)
Siglinda Parathoner (additional)
Gabriele Centi (additional)
Avik Halder (additional)
Eric C. Tyo (additional)
Bing Yang (additional)
Sönke Seifert (additional)
Stefan Vajda (additional)

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Dates

Type	When
Created	9 years ago (Aug. 4, 2016, 3 a.m.)
Deposited	1 year, 4 months ago (April 17, 2024, 6:09 p.m.)
Indexed	6 months, 1 week ago (Feb. 21, 2025, 1:22 p.m.)
Issued	9 years, 8 months ago (Jan. 1, 2016)
Published	9 years, 8 months ago (Jan. 1, 2016)
Published Online	9 years, 8 months ago (Jan. 1, 2016)

Funders 1

U.S. Department of Energy 10.13039/100000015
Region: Americas
gov (National government)
Labels8
1. Energy Department
2. Department of Energy
3. United States Department of Energy
4. ENERGY.GOV
5. US Department of Energy
6. USDOE
7. DOE
8. USADOE
Awards1
1. DE-AC-02-06CH11357

BibTeX

@article{Passalacqua_2016, title={Electrochemical behaviour of naked sub-nanometre sized copper clusters and effect of CO2}, volume={6}, ISSN={2044-4761}, url={http://dx.doi.org/10.1039/c6cy00942e}, DOI={10.1039/c6cy00942e}, number={18}, journal={Catalysis Science & Technology}, publisher={Royal Society of Chemistry (RSC)}, author={Passalacqua, Rosalba and Parathoner, Siglinda and Centi, Gabriele and Halder, Avik and Tyo, Eric C. and Yang, Bing and Seifert, Sönke and Vajda, Stefan}, year={2016}, pages={6977–6985} }

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  "abstract": "<p>In size-controlled naked Cu<sub>5</sub>and Cu<sub>20</sub>nanoclusters the latter show anodic redox processes occurring at much lower potential with respect to Cu<sub>5</sub>, but the latter coordinate effectively CO<sub>2</sub>and allow to reduce CO<sub>2</sub>under cathodic conditions at lower overpotential.</p>",
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