Abstract
The first heterobimetallic complexes comprising interconnected silylene and phosphine donors are reported. In a stepwise fashion, first the silylene coordinates to iron and subsequently the phosphine coordinates to tungsten. Another heterobimetallic complex can be obtained by the insertion of platinum into the P–H bond.
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Dates
Type | When |
---|---|
Created | 9 years, 5 months ago (March 1, 2016, 9:15 a.m.) |
Deposited | 1 year, 4 months ago (April 17, 2024, 5:45 p.m.) |
Indexed | 6 months, 1 week ago (Feb. 21, 2025, 3:08 a.m.) |
Issued | 9 years, 7 months ago (Jan. 1, 2016) |
Published | 9 years, 7 months ago (Jan. 1, 2016) |
Published Online | 9 years, 7 months ago (Jan. 1, 2016) |
Funders
1
Alexander von Humboldt-Stiftung
10.13039/100005156
Region: Europe
pri (Trusts, charities, foundations (both public and private))
Labels
5
- Humboldt-Stiftung
- Humboldt Foundation
- Alexander von Humboldt Foundation
- Humboldt Stiftung
- AvH
Awards
1
- Sofia Kovalevskaja Program
@article{Breit_2016, title={Phosphinosilylenes as a novel ligand system for heterobimetallic complexes}, volume={52}, ISSN={1364-548X}, url={http://dx.doi.org/10.1039/c6cc00601a}, DOI={10.1039/c6cc00601a}, number={32}, journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)}, author={Breit, Nora C. and Eisenhut, Carsten and Inoue, Shigeyoshi}, year={2016}, pages={5523–5526} }